Received February 22,—Read March 15, 1838.
P ix. Disruptive discharge (continued).
1480. Let us now direct our attention
to the general difference of the positive and negative
disruptive discharge, with the object of tracing, as
far as possible, the cause of that difference, and
whether it depends on the charged conductors principally,
or on the interposed dielectric; and as it appears
to be great in air and nitrogen (1476.), let us observe
the phenomena in air first.
1481. The general case is best
understood by a reference to surfaces of considerable
size rather than to points, which involve (as a secondary
effect) the formation of currents (1562). My investigation,
therefore, was carried on with balls and terminations
of different diameters, and the following are some
of the principal results.
1482. If two balls of very different
dimensions, as for instance one-half an inch, and
the other three inches in diameter, be arranged at
the ends of rods so that either can be electrified
by a machine and made to discharge by sparks to the
other, which is at the same time uninsulated; then,
as is well known, far longer sparks are obtained when
the small ball is positive and the large ball negative,
than when the small ball is negative and the large
ball positive. In the former case, the sparks
are 10 or 12 inches in length; in the latter, an inch
or an inch and a half only.
1483. But previous to the description
of further experiments, I will mention two words,
for which with many others I am indebted to a friend,
and which I think it would be expedient to introduce
and use. It is important in ordinary inductive
action, to distinguish at which charged surface the
induction originates and is sustained: i.e.
if two or more metallic balls, or other masses of
matter, are in inductive relation, to express which
are charged originally, and which are brought by them
into the opposite electrical condition. I propose
to call those bodies which are originally charged,
inductric bodies; and those which assume the
opposite state, in consequence of the induction, inducteous
bodies. This distinction is not needful because
there is any difference between the sums of the inductric
and the inducteous forces; but principally because,
when a ball A is inductric, it not merely brings a
ball B, which is opposite to it, into an inducteous
state, but also many other surrounding conductors,
though some of them may be a considerable distance
off, and the consequence is, that the balls do not
bear the same precise relation to each other when,
first one, and then the other, is made the inductric
ball; though, in each case, the same ball be
made to assume the same state.
1484, Another liberty which I may
also occasionally take in language I will explain
and limit. It is that of calling a particular
spark or brush, positive or negative,
according as it may be considered as originating
at a positive or a negative surface. We speak
of the brush as positive or negative when it shoots
out from surfaces previously in those states; and
the experiments of Mr. Wheatstone go to prove that
it really begins at the charged surface, and
from thence extends into the air (1437. 1438.) or
other dielectric. According to my view, sparks
also originate or are determined at one particular
spot (1370.), namely, that where the tension first
rises up to the maximum degree; and when this can be
determined, as in the simultaneous use of large and
small balls, in which case the discharge begins or
is determined by the latter, I would call that discharge
which passes at once, a positive spark, if it
was at the positive surface that the maximum intensity
was first obtained; or a negative spark, if that necessary
intensity was first obtained at the negative surface.
1485. An apparatus was arranged,
as in fi. (Plate VIII.): A and B were brass
balls of very different diameters attached to metal
rods, moving through sockets on insulating pillars,
so that the distance between the balls could be varied
at pleasure. The large ball A, 2 inches in diameter,
was connected with an insulated brass conductor, which
could be rendered positive or negative directly from
a cylinder machine: the small ball B, 0.25 of
an inch in diameter, was connected with a discharging
train (292.) and perfectly uninsulated. The brass
rods sustaining the balls were 0.2 of an inch in thickness.
1486. When the large ball was
positive and inductric (1483.), negative sparks
occurred until the interval was 0.49 of an inch; then
mixed brush and spark between that and 0.51; and from
0.52 and upwards, negative brush alone. When
the large ball was made negative and inductric,
then positive spark alone occurred until the interval
was as great as 1.15 inches; spark and brush from
that up to 1.55; and to have the positive brush alone,
it required an interval of at least 1.65 inches.
1487. The balls A and B were
now changed for each other. Then making the small
ball B inductric positively, the positive sparks
alone continued only up to 0.67; spark and brush occurred
from 0.68 up to 0.72; and positive brush alone from
0.74 and upwards. Rendering the small ball B
inductric and negative, negative sparks alone
occurred up to 0.40; then spark and brush at 0.42;
whilst from 0.44 and upwards the noisy negative brush
alone took place.
1488. We thus find a great difference
as the balls are rendered inductric or inducteous;
the small ball rendered positive inducteously
giving a spark nearly twice as long as that produced
when it was charged positive inductrically, and a
corresponding difference, though not, under the circumstances,
to the same extent, was manifest, when it was rendered
negative.
For similar experiments on different
gases, see 1518.—De.
1489. Other results are, that
the small ball rendered positive gives a much longer
spark than when it is rendered negative, and that the
small ball rendered negative gives a brush more readily
than when positive, in relation to the effect produced
by increasing the distance between the two balls.
1490. When the interval was below
0.4 of an inch, so that the small ball should give
sparks, whether positive or negative, I could not observe
that there was any constant difference, either in
their ready occurrence or the number which passed
in a given time. But when the interval was such
that the small ball when negative gave a brush, then
the discharges from it, as separate negative brushes,
were far more numerous than the corresponding discharges
from it when rendered positive, whether those positive
discharges were as sparks or brushes.
1491. It is, therefore, evident
that, when a ball is discharging electricity in the
form of brushes, the brushes are far more numerous,
and each contains or carries off far less electric
force when the electricity so discharged is negative,
than when it is positive.
1492. In all such experiments
as those described, the point of change from spark
to brush is very much governed by the working state
of the electrical machine and the size of the conductor
connected with the discharging ball. If the machine
be in strong action and the conductor large, so that
much power is accumulated quickly for each discharge,
then the interval is greater at which the sparks are
replaced by brushes; but the general effect is the
same.
For similar experiments in different
gases, see 1510-1517.—Dec.
1838.
1493. These results, though indicative
of very striking and peculiar relations of the electric
force or forces, do not show the relative degrees
of charge which the small ball acquires before discharge
occurs, i.e. they do not tell whether it acquires
a higher condition in the negative, or in the positive
state, immediately preceding that discharge. To
illustrate this important point I arranged two places
of discharge as represented, fig 130. A and D
are brass balls 2 inches diameter, B and C are smaller
brass balls 0.25 of an inch in diameter; the forks
L and R supporting them were of brass wire 0.2 of
an inch in diameter; the space between the large and
small ball on the same fork was 5 inches, that the
two places of discharge n and o might
be sufficiently removed from each other’s influence.
The fork L was connected with a projecting cylindrical
conductor, which could be rendered positive or negative
at pleasure, by an electrical machine, and the fork
R was attached to another conductor, but thrown into
an uninsulated state by connection with a discharging
train (292.). The two intervals or places of
discharge n and o could be varied at
pleasure, their extent being measured by the occasional
introduction of a diagonal scale. It is evident,
that, as the balls A and B connected with the same
conductor are always charged at once, and that discharge
may take place to either of the balls connected with
the discharging train, the intervals of discharge
n and o may be properly compared to each
other, as respects the influence of large and small
balls when charged positively and negatively in air.
1494. When the intervals n
and o were each made = 0.9 of an inch, and
the balls A and B inductric positively, the
discharge was all at n from the small ball
of the conductor to the large ball of the discharging
train, and mostly by positive brush, though once by
a spark. When the balls A and B were made inductric
negatively, the discharge was still from the
same small ball, at n, by a constant negative
brush.
1495. I diminished the intervals
n and o to 0.6 of an inch. When
A and B were inductric positively, all the
discharge was at n as a positive brush:
when A and B were inductric negatively, still
all the discharge was at n, as a negative brush.
1496. The facility of discharge
at the positive and negative small balls, therefore,
did not appear to be very different. If a difference
had existed, there were always two small balls, one
in each state, that the discharge might happen at
that most favourable to the effect. The only
difference was, that one was in the inductric, and
the other in the inducteous state, but whichsoever
happened for the time to be in that state, whether
positive or negative, had the advantage.
1497. To counteract this interfering
influence, I made the interval n = 0.79 and
interval o = 0.58 of an inch. Then, when
the balls A and B were inductric positive,
the discharge was about equal at both intervals.
When, on the other hand, the balls A and B were inductric
negative, there was discharge, still at both,
but most at n, as if the small ball negative
could discharge a little easier than the same ball
positive.
1498. The small balls and terminations
used in these and similar experiments may very correctly
be compared, in their action, to the same balls and
ends when electrified in free air at a much greater
distance from conductors, than they were in those
cases from each other. In the first place, the
discharge, even when as a spark, is, according to my
view, determined, and, so to speak, begins at a spot
on the surface of the small ball (1374.), occurring
when the intensity there has risen up to a certain
maximum degree (1370.); this determination of discharge
at a particular spot first, being easily traced from
the spark into the brush, by increasing the distance,
so as, at last, even to render the time evident which
is necessary for the production of the effect (1436.
1438.). In the next place, the large balls which
I have used might be replaced by larger balls at a
still greater distance, and so, by successive degrees,
may be considered as passing into the sides of the
rooms; these being under general circumstances the
inducteous bodies, whilst the small ball rendered
either positive or negative is the inductric body.
1499. But, as has long been recognised,
the small ball is only a blunt end, and, electrically
speaking, a point only a small ball; so that when a
point or blunt end is throwing out its brushes into
the air, it is acting exactly as the small balls have
acted in the experiments already described, and by
virtue of the same properties and relations.
1500. It may very properly be
said with respect to the experiments, that the large
negative ball is as essential to the discharge as the
small positive ball, and also that the large negative
ball shows as much superiority over the large positive
ball (which is inefficient in causing a spark from
its opposed small negative ball) as the small positive
ball does over the small negative ball; and probably
when we understand the real cause of the difference,
and refer it rather to the condition of the particles
of the dielectric than to the sizes of the conducting
balls, we may find much importance in such an observation.
But for the present, and whilst engaged in investigating
the point, we may admit, what is the fact, that the
forces are of higher intensity at the surfaces of the
smaller balls than at those of the larger (1372. 1374.);
that the former, therefore, determine the discharge,
by first rising up to that exalted condition which
is necessary for it; and that, whether brought to this
condition by induction towards the walls of a room
or the large balls I have used, these may fairly be
compared one with the other in their influence and
actions.
1501. The conclusions I arrive
at are: first, that when two equal small conducting
surfaces equally placed in air are electrified, one
positively and the other negatively, that which is
negative can discharge to the air at a tension a little
lower than that required for the positive ball:
second, that when discharge does take place, much more
passes at each time from the positive than from the
negative surface (1491.). The last conclusion
is very abundantly proved by the optical analysis of
the positive and negative brushes already described
(1468.), the latter set of discharges being found
to recur five or six times oftener than the former.
A very excellent mode of examining
the relation of small positive
and negative surfaces would be by the
use of drops of gum water,
solutions, or other liquids. See
onwards (1581. 1593.).
1502. If, now, a small ball be
made to give brushes or brushy sparks by a powerful
machine, we can, in some measure, understand and relate
the difference perceived when it is rendered positive
or negative. It is known to give when positive
a much larger and more powerful spark than when negative,
and with greater facility (1482.): in fact, the
spark, although it takes away so much more electricity
at once, commences at a tension higher only in a small
degree, if at all. On the other hand, if rendered
negative, though discharge may commence at a lower
degree, it continues but for a very short period,
very little electricity passing away each time.
These circumstances are directly related; for the extent
to which the positive spark can reach, and the size
and extent of the positive brush, are consequences
of the capability which exists of much electricity
passing off at one discharge from the positive surface
(1468. 1501.).
1503. But to refer these effects
only to the form and size of the conductor, would,
according to my notion of induction, be a very imperfect
mode of viewing the whole question (1523. 1600.).
I apprehend that the effects are due altogether to
the mode in which the particles of the interposed
dielectric polarize, and I have already given some
experimental indications of the differences presented
by different electrics in this respect (1475. 1476.).
The modes of polarization, as I shall have occasion
hereafter to show, may be very diverse in different
dielectrics. With respect to common air, what
seems to be the consequence of a superiority in the
positive force at the surface of the small ball, may
be due to the more exalted condition of the negative
polarity of the particles of air, or of the nitrogen
in it (the negative part being, perhaps, more compressed,
whilst the positive part is more diffuse, or vice
versa (1687. &c.)); for such a condition could
determine certain effects at the positive ball which
would not take place to the same degree at the negative
ball, just as well as if the positive ball had possessed
some special and independent power of its own.
1504. The opinion, that the effects
are more likely to be dependent upon the dielectric
than the ball, is supported by the character of the
two discharges. If a small positive ball be throwing
off brushes with ramifications ten inches long, how
can the ball affect that part of a ramification which
is five inches from it? Yet the portion beyond
that place has the same character as that preceding
it, and no doubt has that character impressed by the
same general principle and law. Looking upon the
action of the contiguous particles of a dielectric
as fully proved, I see, in such a ramification, a
propagation of discharge from particle to particle,
each doing for the one next it what was done for it
by the preceding particle, and what was done for the
first particle by the charged metal against which
it was situated.
1505. With respect to the general
condition and relations of the positive and negative
brushes in dense or rare air, or in other media and
gases, if they are produced at different times and
places they are of course independent of each other.
But when they are produced from opposed ends or balls
at the same time, in the same vessel of gas (1470.
1477.), they are frequently related; and circumstances
may be so arranged that they shall be isochronous,
occurring in equal numbers in equal times; or shall
occur in multiples, i.e. with two or three negatives
to one positive; or shall alternate, or be quite irregular.
All these variations I have witnessed; and when it
is considered that the air in the vessel, and also
the glass of the vessel, can take a momentary charge,
it is easy to comprehend their general nature and
cause.
1506. Similar experiments to
those in air (1485. 1493.) were made in different
gases, the results of which I will describe as briefly
as possible. The apparatus is represented fi, consisting of a bell-glass eleven inches in diameter
at the widest part, and ten and a half inches high
up to the bottom of the neck. The balls are lettered,
as in fi, and are in the same relation to each
other; but A and B were on separate sliding wires,
which, however, were generally joined by a cross wire,
w, above, and that connected with the brass
conductor, which received its positive or negative
charge from the machine. The rods of A and B were
graduated at the part moving through the stuffing-box,
so that the application of a diagonal scale applied
there, told what was the distance between these balls
and those beneath them. As to the position of
the balls in the jar, and their relation to each other,
C and D were three and a quarter inches apart, their
height above the pump plate five inches, and the distance
between any of the balls and the glass of the jar one
inch and three quarters at least, and generally more.
The balls A and D were two inches in diameter, as
before (1493.); the balls B and C only 0.15 of an
inch in diameter.
Another apparatus was occasionally
used in connection with that just described, being
an open discharger (fi.), by which a comparison
of the discharge in air and that in gases could be
obtained. The balls E and F, each 0.6 of an inch
in diameter, were connected with sliding rods and
other balls, and were insulated. When used for
comparison, the brass conductor was associated at
the same time with the balls A and B of figure 131
and ball E of this apparatus (fi.); whilst the
balls C, D and F were connected with the discharging
train.
1507. I will first tabulate the
results as to the restraining power of the
gases over discharge. The balls A and C (fi.) were thrown out of action by distance, and the
effects at B and D, or the interval n in the
gas, compared with those at the interval p in
the air, between E and F (fi.). The Table
sufficiently explains itself. It will be understood
that all discharge was in the air, when the interval
there was less than that expressed in the first or
third columns of figures; and all the discharge in
the gas, when the interval in air was greater than
that in the second or fourth column of figures.
At intermediate distances the discharge was occasionally
at both places, i.e. sometimes in the air, sometimes
in the gas.
_____________________________________________________________________
| | |
| | Interval p in parts of an inch |
|_________________|___________________________________________________|
| | | |
| | When the small ball B | When the small ball B |
| Constant inter- | was inductric and | was inductric and |
| val n between | positive the | negative the |
| B and D = 1 | discharge was all | discharge was all |
| inch | at p in at n in | at p in at n in |
| | air before the gas | air before the gas |
| | after | after |
|_________________|_________________________|_________________________|
| | p = | p = | p = | p = |
|In Air | 0.10 | 0.50 | 0.28 | 0.33 |
|In Nitrogen | 0.30 | 0.65 | 0.31 | 0.40 |
|In Oxygen | 0.33 | 0.52 | 0.27 | 0.30 |
|In Hydrogen | 0.20 | 0.10 | 0.22 | 0.24 |
|In Coal Gas | 0.20 | 0.90 | 0.20 | 0.27 |
|In Carbonic Acid | 0.61 | 1.30 | 0.30 | 0.15 |
|_________________|____________|____________|____________|____________|
1508. These results are the same
generally, as far as they go, as those of the like
nature in the last series (1388.), and confirm the
conclusion that different gases restrain discharge
in very different proportions. They are probably
not so good as the former ones, for the glass jar not
being varnished, acted irregularly, sometimes taking
a certain degree of charge as a non-conductor, and
at other times acting as a conductor in the conveyance
and derangement of that charge. Another cause
of difference in the ratios is, no doubt, the relative
sizes of the discharge balls in air; in the former
case they were of very different size, here they were
alike.
1509. In future experiments intended
to have the character of accuracy, the influence of
these circumstances ought to be ascertained, and, above
all things, the gases themselves ought to be contained
in vessels of metal, and not of glass.
1510. The next set of results
are those obtained when the intervals n and
o (fi.) were made equal to each other,
and relate to the greater facility of discharge at
the small ball, when rendered positive or negative
(1493.).
1511. In air, with the
intervals = 0.4 of an inch, A and B being inductric
and positive, discharge was nearly equal at n
and o; when A and B were inductric and negative,
the discharge was mostly at n by negative brush.
When the intervals were = 0.8 of an inch, with A and
B inductric positively, all discharge was at n
by positive brush; with A and B inductric negatively,
all the discharge was at n by a negative brush.
It is doubtful, therefore, from these results, whether
the negative ball has any greater facility than the
positive.
1512. Nitrogen.—Intervals
n and o = 0.4 of an inch: A, B inductric
positive, discharge at both intervals, most at n,
by positive sparks; A, B inductric negative, discharge
equal at n and o. The intervals
made = 0.8 of an inch: A, B inductric positive,
discharge all at n by positive brush; A, B
inductric negative, discharge most at o by positive
brush. In this gas, therefore, though the difference
is not decisive, it would seem that the positive small
ball caused the most ready discharge.
1513. Oxygen.—Intervals
n and o = 0.4 of an inch: A, B inductric
positive, discharge nearly equal; inductric negative,
discharge mostly at n by negative brush.
Made the intervals = 0.8 of an inch: A, B inductric
positive, discharge both at n and o;
inductric negative, discharge all at o by negative
brush. So here the negative small ball seems to
give the most ready discharge.
1514. Hydrogen.—Intervals
n and o = 0.4 of an inch: A, B inductric
positive, discharge nearly equal: inductric negative,
discharge mostly at o. Intervals = 0.8
of an inch: A and B inductric positive, discharge
mostly at n, as positive brush; inductric negative,
discharge mostly at o, as positive brush.
Here the positive discharge seems most facile.
1515. Coal gas.—n
and o = 0.4 of an inch: A, B inductric
positive, discharge nearly all at o by negative
spark: A, B inductric negative, discharge nearly
all at n by negative spark. Intervals =
0.8 of an inch, and A, B inductric positive, discharge
mostly at o by negative brush: A, B inductric
negative, discharge all at n by negative brush.
Here the negative discharge most facile.
1516. Carbonic acid gas.—n
and o = 0.1 of an inch: A, B inductric
positive, discharge nearly all at o, or negative:
A, B inductric negative, discharge nearly all at n,
or negative. Intervals = 0.8 of an inch:
A, B inductric positive, discharge mostly at o,
or negative. A, B inductric negative, discharge
all at n, or negative. In this case the
negative had a decided advantage in facility of discharge.
1517. Thus, if we may trust this
form of experiment, the negative small ball has a
decided advantage in facilitating disruptive discharge
over the positive small ball in some gases, as in
carbonic acid gas and coal gas (1399.), whilst in
others that conclusion seems more doubtful; and in
others, again, there seems a probability that the positive
small ball may be superior. All these results
were obtained at very nearly the same pressure of
the atmosphere.
1518. I made some experiments
in these gases whilst in the air jar (fi.),
as to the change from spark to brush, analogous to
those in the open air already described (1486. 1487.).
I will give, in a Table, the results as to when brush
began to appear mingled with the spark; but the after
results were so varied, and the nature of the discharge
in different gases so different, that to insert the
results obtained without further investigation, would
be of little use. At intervals less than those
expressed the discharge was always by spark.
_______________________________________________________________________
| | | |
| | Discharge between | Discharge between |
| | balls B and D. | balls A and C. |
| |___________________________|___________________________|
| | | | | |
| | Small ball | Small ball | Large ball | Large ball |
| | B inductric | B inductric | A inductric | A inductric |
| | pos. | neg. | pos. | neg. |
|_______________|_____________|_____________|_____________|_____________|
| | | | | |
| Air | 0.55 | 0.30 | 0.40 | 0.75 |
| Nitrogen | 0.30 | 0.40 | 0.52 | 0.41 |
| Oxygen | 0.70 | 0.30 | 0.45 | 0.82 |
| Hydrogen | 0.20 | 0.10 | | |
| Coal gas | 0.13 | 0.30 | 0.30 | 0.44 |
| Carbonic acid | 0.82 | 0.43 | 1.60 | {above 1.80;|
| | | | | had not |
| | | | | space.) |
|_______________|_____________|_____________|_____________|_____________|
1519. It is to be understood
that sparks occurred at much higher intervals than
these; the table only expresses that distance beneath
which all discharge was as spark. Some curious
relations of the different gases to discharge are
already discernible, but it would be useless to consider
them until illustrated by further experiments.
1520. I ought not to omit noticing
here, that Professor Belli of Milan has published
a very valuable set of experiments on the relative
dissipation of positive and negative electricity in
the air; he finds the latter far more ready, in
this respect, than the former.
Bibliothèque Universelle,
1836, September, .
1521. I made some experiments
of a similar kind, but with sustained high charges;
the results were less striking than those of Signore
Belli, and I did not consider them as satisfactory.
I may be allowed to mention, in connexion with the
subject, an interfering effect which embarrassed me
for a long time. When I threw positive electricity
from a given point into the air, a certain intensity
was indicated by an electrometer on the conductor
connected with the point, but as the operation continued
this intensity rose several degrees; then making the
conductor negative with the same point attached to
it, and all other things remaining the same, a certain
degree of tension was observed in the first instance,
which also gradually rose as the operation proceeded.
Returning the conductor to the positive state, the
tension was at first low, but rose as before; and so
also when again made negative.
1522. This result appeared to
indicate that the point which had been giving off
one electricity, was, by that, more fitted for a short
time to give off the other. But on closer examination
I found the whole depended upon the inductive reaction
of that air, which being charged by the point, and
gradually increasing in quantity before it, as the
positive or negative issue was continued, diverted
and removed a part of the inductive action of the
surrounding wall, and thus apparently affected the
powers of the point, whilst really it was the dielectric
itself that was causing the change of tension.
1523. The results connected with
the different conditions of positive and negative
discharge will have a far greater influence on the
philosophy of electrical science than we at present
imagine, especially if, as I believe, they depend
on the peculiarity and degree of polarized condition
which the molecules of the dielectrics concerned acquire
(1503. 1600.). Thus, for instance, the relation
of our atmosphere and the earth within it, to the
occurrence of spark or brush, must be especial and
not accidental (1464.). It would not else consist
with other meteorological phenomena, also of course
dependent on the special properties of the air, and
which being themselves in harmony the most perfect
with the functions of animal and vegetable life, are
yet restricted in their actions, not by loose regulations,
but by laws the most precise.
1524. Even in the passage through
air of the voltaic current we see the peculiarities
of positive and negative discharge at the two charcoal
points; and if these discharges are made to take place
simultaneously to mercury, the distinction is still
more remarkable, both as to the sound and the quantity
of vapour produced.
1525. It seems very possible
that the remarkable difference recently observed and
described by my friend Professor Daniell, namely,
that when a zinc and a copper ball, the same in size,
were placed respectively in copper and zinc spheres,
also the same in size, and excited by electrolytes
or dielectrics of the same strength and nature, the
zinc ball far surpassed the zinc sphere in action,
may also be connected with these phenomena; for it
is not difficult to conceive how the polarity of the
particles shall be affected by the circumstance of
the positive surface, namely the zinc, being the larger
or the smaller of the two inclosing the electrolyte.
It is even possible, that with different electrolytes
or dielectrics the ratio may be considerably varied,
or in some cases even inverted.
Philosophical Transactions, 1838,
.
Glow discharge.
1526. That form of disruptive
discharge which appears as a glow (1359. 1405.),
is very peculiar and beautiful: it seems to depend
on a quick and almost continuous charging of the air
close to, and in contact with, the conductor.
1527. Diminution of the charging
surface will produce it. Thus, when a rod
0.3 of an inch in diameter, with a rounded termination,
was rendered positive in free air, it gave fine brushes
from the extremity, but occasionally these disappeared,
and a quiet phosphorescent continuous glow took their
place, covering the whole of the end of the wire, and
extending a very small distance from the metal into
the air. With a rod 0.2 of an inch in diameter
the glow was more readily produced. With still
smaller rods, and also with blunt conical points,
it occurred still more readily; and with a fine point
I could not obtain the brush in free air, but only
this glow. The positive glow and the positive
star are, in fact, the same.
1528. Increase of power in the
machine tends to produce the glow; for rounded
terminations which will give only brushes when the
machine is in weak action, will readily give the glow
when it is in good order.
1529. Rarefaction of the air
wonderfully favours the glow phenomena. A brass
ball, two and a half inches in diameter, being made
positively inductric in an air-pump receiver, became
covered with glow over an area of two inches in diameter,
when the pressure was reduced to 4.4 inches of mercury.
By a little adjustment the ball could be covered all
over with this light. Using a brass ball 1.25
inches in diameter, and making it inducteously positive
by an inductric negative point, the phenomena, at
high degrees of rarefaction, were exceedingly beautiful.
The glow came over the positive ball, and gradually
increased in brightness, until it was at last very
luminous; and it also stood up like a low flame, half
an inch or more in height. On touching the sides
of the glass jar this lambent flame was affected,
assumed a ring form, like a crown on the top of the
ball, appeared flexible, and revolved with a comparatively
slow motion, i.e. about four or five times in
a second. This ring-shape and revolution are
beautifully connected with the mechanical currents
(1576.) taking place within the receiver. These
glows in rarefied air are often highly exalted in
beauty by a spark discharge at the conductor (1551.
Note.).
1530. To obtain a negative
glow in air at common pressures is difficult.
I did not procure it on the rod 0.3 of an inch in diameter
by my machine, nor on much smaller rods; and it is
questionable as yet, whether, even on fine points,
what is called the negative star is a very reduced
and minute, but still intermitting brush, or a glow
similar to that obtained on a positive point.
1531. In rarefied air the negative
glow can easily be obtained. If the rounded ends
of two metal rods, about of an inch in diameter,
are introduced into a globe or jar (the air within
being rarefied), and being opposite to each other,
are about four inches apart, the glow can be obtained
on both rods, covering not only the ends, but an inch
or two of the part behind. On using balls
in the air-pump jar, and adjusting the distance and
exhaustion, the negative ball could be covered with
glow, whether it were the inductric or the inducteous
surface.
1532. When rods are used it is
necessary to be aware that, if placed concentrically
in the jar or globe, the light on one rod is often
reflected by the sides of the vessel on to the other
rod, and makes it apparently luminous, when really
it is not so. This effect may be detected by shifting
the eye at the time of observation, or avoided by using
blackened rods.
1533. It is curious to observe
the relation of glow, brush, and spark
to each other, as produced by positive or negative
surfaces; thus, beginning with spark discharge, it
passes into brush much sooner when the surface at
which the discharge commences (1484.) is negative,
than it does when positive; but proceeding onwards
in the order of change, we find that the positive
brush passes into glow long before the negative
brush does. So that, though each presents the
three conditions in the same general order, the series
are not precisely the same. It is probable, that,
when these points are minutely examined, as they must
be shortly, we shall find that each different gas
or dielectric presents its own peculiar results, dependent
upon the mode in which its particles assume polar electric
condition.
1534. The glow occurs in all
gases in which I have looked for it. These are
air, nitrogen, oxygen, hydrogen, coal gas, carbonic
acid, muriatic acid, sulphurous acid and ammonia.
I thought also that I obtained it in oil of turpentine,
but if so it was very dull and small.
1535. The glow is always accompanied
by a wind proceeding either directly out from the
glowing part, or directly towards it; the former being
the most general case. This takes place even
when the glow occurs upon a ball of considerable size:
and if matters be so arranged that the ready and regular
access of air to a part exhibiting the glow be interfered
with or prevented, the glow then disappears.
1536. I have never been able
to analyse or separate the glow into visible elementary
intermitting discharges (1427. 1433.), nor to obtain
the other evidence of intermitting action, namely
an audible sound (1431.). The want of success,
as respects trials made by ocular means, may depend
upon the large size of the glow preventing the separation
of the visible images: and, indeed, if it does
intermit, it is not likely that all parts intermit
at once with a simultaneous regularity.
1537. All the effects tend to
show, that glow is due to a continuous charge
or discharge of air; in the former case being accompanied
by a current from, and in the latter by one to, the
place of the glow. As the surrounding air comes
up to the charged conductor, on attaining that spot
at which the tension of the particles is raised to
the sufficient degree (1370. 1410.), it becomes charged,
and then moves off, by the joint action of the forces
to which it is subject; and, at the same time that
it makes way for other particles to come and be charged
in turn, actually helps to form that current by which
they are brought into the necessary position.
Thus, through the regularity of the forces, a constant
and quiet result is produced; and that result is,
the charging of successive portions of air, the production
of a current, and of a continuous glow.
1538. I have frequently been
able to make the termination of a rod, which, when
left to itself, would produce a brush, produce in preference
a glow, simply by aiding the formation of a current
of air at its extremity; and, on the other hand, it
is not at all difficult to convert the glow into brushes,
by affecting the current of air (1574. 1579.) or the
inductive action near it.
1539. The transition from glow,
on the one hand, to brush and spark, on the other,
and, therefore, their connexion, may be established
in various ways. Those circumstances which tend
to facilitate the charge of the air by the excited
conductor, and also those which tend to keep the tension
at the same degree notwithstanding the discharge,
assist in producing the glow; whereas those which
tend to resist the charge of the air or other dielectric,
and those which favour the accumulation of electric
force prior to discharge, which, sinking by that act,
has to be exalted before the tension can again acquire
the requisite degree, favour intermitting discharge,
and, therefore, the production of brush or spark.
Thus, rarefaction of the air, the removal of large
conducting surfaces from the neighbourhood of the
glowing termination, the presentation of a sharp point
towards it, help to sustain or produce the glow:
but the condensation of the air, the presentation
of the hand or other large surface, the gradual approximation
of a discharging ball, tend to convert the glow into
brush or even spark. All these circumstances
may be traced and reduced, in a manner easily comprehensible,
to their relative power of assisting to produce, either
a continuous discharge to the air, which gives
the glow; or an interrupted one, which produces
the brush, and, in a more exalted condition, the spark.
1540. The rounded end of a brass
rod, 0.3 of an inch in diameter, was covered with
a positive glow by the working of an electrical machine:
on stopping the machine, so that the charge of the
connected conductor should fall, the glow changed
for a moment into brushes just before the discharge
ceased altogether, illustrating the necessity for a
certain high continuous charge, for a certain sized
termination. Working the machine so that the
intensity should be just low enough to give continual
brushes from the end in free air, the approach of
a fine point changed these brushes into a glow.
Working the machine so that the termination presented
a continual glow in free air, the gradual approach
of the hand caused the glow to contract at the very
end of the wire, then to throw out a luminous point,
which, becoming a foot stalk (1426.), finally produced
brushes with large ramifications. All these results
are in accordance with what is stated above (1539.).
1541. Greasing the end of a rounded
wire will immediately make it produce brushes instead
of glow. A ball having a blunt point which can
be made to project more or less beyond its surface,
at pleasure, can be made to produce every gradation
from glow, through brush, to spark.
1542. It is also very interesting
and instructive to trace the transition from spark
to glow, through the intermediate condition of stream,
between ends in a vessel containing air more or less
rarefied; but I fear to be prolix.
1543. All the effects show, that
the glow is in its nature exactly the same as the
luminous part of a brush or ramification, namely a
charging of air; the only difference being, that the
glow has a continuous appearance from the constant
renewal of the same action in the same place, whereas
the ramification is due to a momentary, independent
and intermitting action of the same kind.
Dark discharge.
1544. I will now notice a very
remarkable circumstance in the luminous discharge
accompanied by negative glow, which may, perhaps, be
correctly traced hereafter into discharges of much
higher intensity. Two brass rods, 0.3 of an inch
in diameter, entering a glass globe on opposite sides,
had their ends brought into contact, and the air about
them very much rarefied. A discharge of electricity
from the machine was then made through them, and whilst
that was continued the ends were separated from each
other. At the moment of separation a continuous
glow came over the end of the negative rod, the positive
termination remaining quite dark. As the distance
was increased, a purple stream or haze appeared on
the end of the positive rod, and proceeded directly
outwards towards the negative rod; elongating as the
interval was enlarged, but never joining the negative
glow, there being always a short dark space between.
This space, of about 1/16th or 1/20th of an inch,
was apparently invariable in its extent and its position,
relative to the negative rod; nor did the negative
glow vary. Whether the negative end were inductric
or inducteous, the same effect was produced. It
was strange to see the positive purple haze diminish
or lengthen as the ends were separated, and yet this
dark space and the negative glow remain unaltered
(fi.
1545. Two balls were then used
in a large air-pump receiver, and the air rarefied.
The usual transitions in the character of the discharge
took place; but whenever the luminous stream, which
appears after the spark and the brush have ceased,
was itself changed into glow at the balls, the dark
space occurred, and that whether the one or the other
ball was made inductric, or positive, or negative.
1546. Sometimes when the negative
ball was large, the machine in powerful action, and
the rarefaction high, the ball would be covered over
half its surface with glow, and then, upon a hasty
observation, would seem to exhibit no dark space:
but this was a deception, arising from the overlapping
of the convex termination of the negative glow and
the concave termination of the positive stream.
More careful observation and experiment have convinced
me, that when the negative glow occurs, it never visibly
touches the luminous part of the positive discharge,
but that the dark space is always there.
1547. This singular separation
of the positive and negative discharge, as far as
concerns their luminous character, under circumstances
which one would have thought very favourable to their
coalescence, is probably connected with their differences
when in the form of brush, and is perhaps even dependent
on the same cause. Further, there is every likelihood
that the dark parts which occur in feeble sparks are
also connected with these phenomena. To understand
them would be very important, for it is quite clear
that in many of the experiments, indeed in all that
I have quoted, discharge is taking place across the
dark part of the dielectric to an extent quite equal
to what occurs in the luminous part. This difference
in the result would seem to imply a distinction in
the modes by which the two electric forces are brought
into equilibrium in the respective parts; and looking
upon all the phenomena as giving additional proofs,
that it is to the condition of the particles of the
dielectric we must refer for the principles of induction
and discharge, so it would be of great importance
if we could know accurately in what the difference
of action in the dark and the luminous parts consisted.
See Professor Johnson’s experiments.
Silliman’s Journal, xxv. .
1548. The dark discharge through
air (1552.), which in the case mentioned is very evident
(1544.), leads to the inquiry, whether the particles
of air are generally capable of effecting discharge
from one to another without becoming luminous; and
the inquiry is important, because it is connected
with that degree of tension which is necessary to originate
discharge (1368. 1370.). Discharge between air
and conductors without luminous appearances are
very common; and non-luminous discharges by carrying
currents of air and other fluids (1562. 1595.) are
also common enough: but these are not cases in
point, for they are not discharges between insulating
particles.
1549. An arrangement was made
for discharge between two balls (1485.) (fi.)
but, in place of connecting the inducteous ball directly
with the discharging train, it was put in communication
with the inside coating of a Leyden jar, and the discharging
train with the outside coating. Then working
the machine, it was found that whenever sonorous and
luminous discharge occurred at the balls A B, the
jar became charged; but that when these did not occur,
the jar acquired no charge: and such was the case
when small rounded terminations were used in place
of the balls, and also in whatever manner they were
arranged. Under these circumstances, therefore,
discharge even between the air and conductors was always
luminous.
1550. But in other cases, the
phenomena are such as to make it almost certain, that
dark discharge can take place across air. If the
rounded end of a metal rod, 0.15 of an inch in diameter,
be made to give a good negative brush, the approach
of a smaller end or a blunt point opposite to it will,
at a certain distance, cause a diminution of the brush,
and a glow will appear on the positive inducteous
wire, accompanied by a current of air passing from
it. Now, as the air is being charged both at the
positive and negative surfaces, it seems a reasonable
conclusion, that the charged portions meet somewhere
in the interval, and there discharge to each other,
without producing any luminous phenomena. It is
possible, however, that the air electrified positively
at the glowing end may travel on towards the negative
surface, and actually form that atmosphere into which
the visible negative brushes dart, in which case dark
discharge need not, of necessity, occur. But
I incline to the former opinion, and think, that the
diminution in size of the negative brush, as the positive
glow comes on to the end of the opposed wire, is in
favour of that view.
1551. Using rarefied air as the
dielectric, it is very easy to obtain luminous phenomena
as brushes, or glow, upon both conducting balls or
terminations, whilst the interval is dark, and that,
when the action is so momentary that I think we cannot
consider currents as effecting discharge across the
dark part. Thus if two balls, about an inch in
diameter, and 4 or more inches apart, have the air
rarefied about them, and are then interposed in the
course of discharge, an interrupted or spark current
being produced at the machine, each termination
may be made to show luminous phenomena, whilst more
or less of the interval is quite dark. The discharge
will pass as suddenly as a retarded spark (295. 334.),
i.e. in an interval of time almost inappreciably
small, and in such a case, I think it must have passed
across the dark part as true disruptive discharge,
and not by convection.
By spark current I mean one passing
in a series of spark between the conductor of the
machine and the apparatus: by a continuous current
one that passes through metallic conductors, and in
that respect without interruption at the same place.
1552. Hence I conclude that dark
disruptive discharge may occur (1547. 1550.); and
also, that, in the luminous brush, the visible ramifications
may not show the full extent of the disruptive discharge
(1444. 1452.), but that each may have a dark outside,
enveloping, as it were, every part through which the
discharge extends. It is probable, even, that
there are such things as dark discharges analogous
in form to the brush and the spark, but not luminous
in any part (1445.).
1553. The occurrence of dark
discharge in any case shows at how low a tension disruptive
discharge may occur (1548,), and indicates that the
light of the ultimate brush or spark is in no relation
to the intensity required (1368. 1370.). So to
speak, the discharge begins in darkness, and the light
is a mere consequence of the quantity which, after
discharge has commenced, flows to that spot and there
finds its most facile passage (1418. 1435.).
As an illustration of the growth generally of discharge,
I may remark that, in the experiments on the transition
in oxygen of the discharge from spark to brush (1518.),
every spark was immediately preceded by a short brush.
1554. The phenomena relative
to dark discharge in other gases, though differing
in certain characters from those in air, confirm the
conclusions drawn above. The two rounded terminations
(1544.) (fi.), were placed in muriatic acid
gas (1445. 1463.) at the pressure of 6.5 inches
of mercury, and a continuous machine current of electricity
sent through the apparatus: bright sparks occurred
until the interval was about or above an inch, when
they were replaced by squat brushy intermitting glows
upon both terminations, with a dark part between.
When the current at the machine was in spark, then
each spark caused a discharge across the muriatic acid
gas, which, with a certain interval, was bright; with
a larger interval, was straight across and flamy,
like a very exhausted and sudden, but not a dense
sharp spark; and with a still larger interval, produced
a feeble brush on the inductric positive end, and
a glow on the inducteous negative end, the dark part
being between (1544.); and at such times, the spark
at the conductor, instead of being sudden and sonorous,
was dull and quiet (334.).
1555. On introducing more muriatic
acid gas, until the pressure was 29.97 inches, the
same terminations gave bright sparks within at small
distances; but when they were about an inch or more
apart, the discharge was generally with very small
brushes and glow, and frequently with no light at all,
though electricity had passed through the gas.
Whenever the bright spark did pass through the muriatic
acid gas at this pressure, it was bright throughout,
presenting no dark or dull space.
1556. In coal gas, at
common pressures, when the distance was about an inch,
the discharge was accompanied by short brushes on the
ends, and a dark interval of half an inch or more
between them, notwithstanding the discharge had the
sharp quick sound of a dull spark, and could not have
depended in the dark part on convection (1562.).
1557. This gas presents several
curious points in relation to the bright and dark
parts of spark discharge. When bright sparks passed
between the rod ends 0.3 of an inch in diameter (1544.),
very sudden dark parts would occur next to the brightest
portions of the spark. Again with these ends
and also with balls (1422.), the bright sparks would
be sometimes red, sometimes green, and occasionally
green and red in different parts of the same spark.
Again, in the experiments described (1518.), at certain
intervals a very peculiar pale, dull, yet sudden discharge
would pass, which, though apparently weak, was very
direct in its course, and accompanied by a sharp snapping
noise, as if quick in its occurrence.
1558. Hydrogen frequently gave
peculiar sparks, one part being bright red, whilst
the other was a dull pale gray, or else the whole spark
was dull and peculiar.
1559. Nitrogen presents a very
remarkable discharge, between two balls of the respective
diameters of 0.15 and 2 inches (1506. 1518.), the smaller
one being rendered negative either directly inducteously.
The peculiar discharge occurs at intervals between
0.42 and 0.68, and even at 1.4 inches when the large
ball was inductric positively; it consisted of a little
brushy part on the small negative ball, then a dark
space, and lastly a dull straight line on the large
positive ball (fi.). The position of the
dark space was very constant, and is probably in direct
relation to the dark space described when negative
glow was produced (1544.). When by any circumstance
a bright spark was determined, the contrast with the
peculiar spark described was very striking; for it
always had a faint purple part, but the place of this
part was constantly near the positive ball.
1560. Thus dark discharge appears
to be decidedly established. But its establishment
is accompanied by proofs that it occurs in different
degrees and modes in different gases. Hence then
another specific action, added to the many (1296.
1398. 1399. 1423. 1454. 1503.) by which the electrical
relations of insulating dielectrics are distinguished
and established, and another argument in favour of
that molecular theory of induction, which is at present
under examination.
I cannot resist referring here by
a note to Biot’s philosophical
view of the nature of the light of the
electric discharge, Annales de
Chimie, liii. .
1561. What I have had to say
regarding disruptive discharge has extended to some
length, but I hope will be excused in consequence of
the importance of the subject. Before concluding
my remarks, I will again intimate in the form of a
query, whether we have not reason to consider the tension
or retention and after discharge in air or other insulating
dielectrics, as the same thing with retardation and
discharge in a metal wire, differing only, but almost
infinitely, in degree (1334. 1336.). In other
words, can we not, by a gradual chain of association,
carry up discharge from its occurrence in air, through
spermaceti and water, to solutions, and then on to
chlorides, oxides and metals, without any essential
change in its character; and, at the same time, connecting
the insensible conduction of air, through muriatic
acid gas and the dark discharge, with the better conduction
of spermaceti, water, and the all but perfect conduction
of the metals, associate the phenomena at both extremes?
and may it not be, that the retardation and ignition
of a wire are effects exactly correspondent in their
nature to the retention of charge and spark in air?
If so, here again the two extremes in property amongst
dielectrics will be found to be in intimate relation,
the whole difference probably depending upon the mode
and degree in which their particles polarize under
the influence of inductive actions (1338. 1603. 1610.).
P x. Convection, or carrying discharge.
1562. The last kind of discharge
which I have to consider is that effected by the motion
of charged particles from place to place. It is
apparently very different in its nature to any of
the former modes of discharge (1319.), but, as the
result is the same, may be of great importance in
illustrating, not merely the nature of discharge itself,
but also of what we call the electric current.
It often, as before observed, in cases of brush and
glow (1440. 1535.), joins its effect to that of disruptive
discharge, to complete the act of neutralization amongst
the electric forces.
1563. The particles which being
charged, then travel, may be either of insulating
or conducting matter, large or small. The consideration
in the first place of a large particle of conducting
matter may perhaps help our conceptions.
1564. A copper boiler 3 feet
in diameter was insulated and electrified, but so
feebly, that dissipation by brushes or disruptive discharge
did not occur at its edges or projecting parts in
a sensible degree. A brass ball, 2 inches in
diameter, suspended by a clean white silk thread, was
brought towards it, and it was found that, if the
ball was held for a second or two near any part of
the charged surface of the boiler, at such distance
(two inches more or less) as not to receive any direct
charge from it, it became itself charged, although
insulated the whole time; and its electricity was
the reverse of that of the boiler.
1565. This effect was the strongest
opposite the edges and projecting parts of the boiler,
and weaker opposite the sides, or those extended portions
of the surface which, according to Coulomb’s
results, have the weakest charge. It was very
strong opposite a rod projecting a little way from
the boiler. It occurred when the copper was charged
negatively as well as positively: it was produced
also with small balls down to 0.2 of an inch and less
in diameter, and also with smaller charged conductors
than the copper. It is, indeed, hardly possible
in some cases to carry an insulated ball within an
inch or two of a charged plane or convex surface without
its receiving a charge of the contrary kind to that
of the surface.
1566. This effect is one of induction
between the bodies, not of communication. The
ball, when related to the positive charged surface
by the intervening dielectric, has its opposite sides
brought into contrary states, that side towards the
boiler being negative and the outer side positive.
More inductric action is directed towards it than would
have passed across the same place if the ball had
not been there, for several reasons; amongst others,
because, being a conductor, the resistance of the
particles of the dielectric, which otherwise would
have been there, is removed (1298.); and also, because
the reacting positive surface of the ball being projected
further out from the boiler than when there is no
introduction of conducting matter, is more free therefore
to act through the rest of the dielectric towards
surrounding conductors, and so favours the exaltation
of that inductric polarity which is directed in its
course. It is, as to the exaltation of force
upon its outer surface beyond that upon the inductric
surface of the boiler, as if the latter were itself
protuberant in that direction. Thus it acquires
a state like, but higher than, that of the surface
of the boiler which causes it; and sufficiently exalted
to discharge at its positive surface to the air, or
to affect small particles, as it is itself affected
by the boiler, and they flying to it, take a charge
and pass off; and so the ball, as a whole, is brought
into the contrary inducteous state. The consequence
is, that, if free to move, its tendency, under the
influence of all the forces, to approach the boiler
is increased, whilst it at the same time becomes more
and more exalted in its condition, both of polarity
and charge, until, at a certain distance, discharge
takes place, it acquires the same state as the boiler,
is repelled, and passing to that conductor most favourably
circumstanced to discharge it, there resumes its first
indifferent condition.
1567. It seems to me, that the
manner in which inductric bodies affect uncharged
floating or moveable conductors near them, is very
frequently of this nature, and generally so when it
ends in a carrying operation (1562. 1602.). The
manner in which, whilst the dominant inductric body
cannot give off its electricity to the air, the inducteous
body can effect the discharge of the same kind
of force, is curious, and, in the case of elongated
or irregularly shaped conductors, such as filaments
or particles of dust, the effect will often be very
ready, and the consequent attraction immediate.
1568. The effect described is
also probably influential in causing those variations
in spark discharge referred to in the last series (1386.
1390. 1391.): for if a particle of dust were
drawn towards the axis of induction between the balls,
it would tend, whilst at some distance from that axis,
to commence discharge at itself, in the manner described
(1566.), and that commencement might so far facilitate
the act (1417. 1420.) as to make the complete discharge,
as spark, pass through the particle, though it might
not be the shortest course from ball to ball.
So also, with equal balls at equal distances, as in
the experiments of comparison already described (1493.
1506.), a particle being between one pair of balls
would cause discharge there in preference; or even
if a particle were between each, difference of size
or shape would give one for the time a predominance
over the other.
1569. The power of particles
of dust to carry off electricity in cases of high
tension is well known, and I have already mentioned
some instances of the kind in the use of the inductive
apparatus (1201.). The general operation is very
well shown by large light objects, as the toy called
the electrical spider; or, if smaller ones are wanted
for philosophical investigation, by the smoke of a
glowing green wax taper, which, presenting a successive
stream of such particles, makes their course visible.
1570. On using oil of turpentine
as the dielectric, the action and course of small
conducting carrying particles in it can be well observed.
A few short pieces of thread will supply the place
of carriers, and their progressive action is exceedingly
interesting.
1571. A very striking effect
was produced on oil of turpentine, which, whether
it was due to the carrying power of the particles in
it, or to any other action of them, is perhaps as
yet doubtful. A portion of that fluid in a glass
vessel had a large uninsulated silver dish at the bottom,
and an electrified metal rod with a round termination
dipping into it at the top. The insulation was
very good, and the attraction and other phenomena
striking. The rod end, with a drop of gum water
attached to it, was then electrified in the fluid;
the gum water soon spun off in fine threads, and was
quickly dissipated through the oil of turpentine.
By the time that four drops had in this way been commingled
with a pint of the dielectric, the latter had lost
by far the greatest portion of its insulating power;
no sparks could be obtained in the fluid; and all
the phenomena dependent upon insulation had sunk to
a low degree. The fluid was very slightly turbid.
Upon being filtered through paper only, it resumed
its first clearness, and now insulated as well as
before. The water, therefore, was merely diffused
through the oil of turpentine, not combined with or
dissolved in it: but whether the minute particles
acted as carriers, or whether they were not rather
gathered together in the line of highest inductive
tension (1350.), and there, being drawn into elongated
forms by the electric forces, combined their effects
to produce a band of matter having considerable conducting
power, as compared with the oil of turpentine, is as
yet questionable.
1572. The analogy between the
action of solid conducting carrying particles and
that of the charged particles of fluid insulating substances,
acting as dielectrics, is very evident and simple;
but in the latter case the result is, necessarily,
currents in the mobile media. Particles are brought
by inductric action into a polar state; and the latter,
after rising to a certain tension (1370.), is followed
by the communication of a part of the force originally
on the conductor; the particles consequently become
charged, and then, under the joint influence of the
repellent and attractive forces, are urged towards
a discharging place, or to that spot where these inductric
forces are most easily compensated by the contrary
inducteous forces.
1573. Why a point should be so
exceedingly favourable to the production of currents
in a fluid insulating dielectric, as air, is very evident.
It is at the extremity of the point that the intensity
necessary to charge the air is first acquired (1374.);
it is from thence that the charged particle recedes;
and the mechanical force which it impresses on the
air to form a current is in every way favoured by
the shape and position of the rod, of which the point
forms the termination. At the same time, the point,
having become the origin of an active mechanical force,
does, by the very act of causing that force, namely,
by discharge, prevent any other part of the rod from
acquiring the same necessary condition, and so preserves
and sustains its own predominance.
1574. The very varied and beautiful
phenomena produced by sheltering or enclosing the
point, illustrate the production of the current exceedingly
well, and justify the same conclusions; it being remembered
that in such cases the effect upon the discharge is
of two kinds. For the current may be interfered
with by stopping the access of fresh uncharged air,
or retarding the removal of that which has been charged,
as when a point is electrified in a tube of insulating
matter closed at one extremity; or the electric
condition of the point itself may be altered by
the relation of other parts in its neighbourhood,
also rendered electric, as when the point is in a
metal tube, by the metal itself, or when it is in the
glass tube, by a similar action of the charged parts
of the glass, or even by the surrounding air which
has been charged, and which cannot escape.
1575. Whenever it is intended
to observe such inductive phenomena in a fluid dielectric
as have a direct relation to, and dependence upon,
the fluidity of the medium, such, for instance, as
discharge from points, or attractions and repulsions,
&c., then the mass of the fluid should be great, and
in such proportion to the distance between the inductric
and inducteous surfaces as to include all the lines
of inductive force (1369.) between them; otherwise,
the effects of currents, attraction, &c., which are
the resultants of all these forces, cannot be obtained.
The phenomena, which occur in the open air, or in
the middle of a globe filled with oil of turpentine,
will not take place in the same media if confined
in tubes of glass, shell-lac, sulphur, or
other such substances, though they be excellent insulating
dielectrics; nor can they be expected: for in
such cases, the polar forces, instead of being all
dispersed amongst fluid particles, which tend to move
under their influence, are now associated in many
parts with particles that, notwithstanding their tendency
to motion, are constrained by their solidity to remain
quiescent.
1576. The varied circumstances
under which, with conductors differently formed and
constituted, currents can occur, all illustrate the
same simplicity of production. A ball,
if the intensity be raised sufficiently on its surface,
and that intensity be greatest on a part consistent
with the production of a current of air up to and
off from it, will produce the effect like a point
(1537); such is the case whenever the glow occurs upon
a ball, the current being essential to that phenomenon.
If as large a sphere as can well be employed with
the production of glow be used, the glow will appear
at the place where the current leaves the ball, and
that will be the part directly opposite to the connection
of the ball and rod which supports it; but by increasing
the tension elsewhere, so as to raise it above the
tension upon that spot, which can easily be effected
inductively, then the place of the glow and the direction
of the current will also change, and pass to that
spot which for the time is most favourable for their
production (1591.).
1577. For instance, approaching
the hand towards the ball will tend to cause brush
(1539.), but by increasing the supply of electricity
the condition of glow may be preserved; then on moving
the hand about from side to side the position of the
glow will very evidently move with it.
1578. A point brought towards
a glowing ball would at twelve or fourteen inches
distance make the glow break into brush, but when still
nearer, glow was reproduced, probably dependent upon
the discharge of wind or air passing from the point
to the ball, and this glow was very obedient to the
motion of the point, following it in every direction.
1579. Even a current of wind
could affect the place of the glow; for a varnished
glass tube being directed sideways towards the ball,
air was sometimes blown through it at the ball and
sometimes not. In the former case, the place
of the glow was changed a little, as if it were blown
away by the current, and this is just the result which
might have been anticipated. All these effects
illustrate beautifully the general causes and relations,
both of the glow and the current of air accompanying
it (1574.).
1580. Flame facilitates the production
of a current in the dielectric surrounding it.
Thus, if a ball which would not occasion a current
in the air have a flame, whether large or small, formed
on its surface, the current is produced with the greatest
ease; but not the least difficulty can occur in comprehending
the effective action of the flame in this case, if
its relation, as part of the surrounding dielectric,
to the electrified ball, be but for a moment considered
(1375. 1380.).
1581. Conducting fluid terminations,
instead of rigid points, illustrate in a very beautiful
manner the formation of the currents, with their effects
and influence in exalting the conditions under which
they were commenced. Let the rounded end of a
brass rod, 0.3 of an inch or thereabouts in diameter,
point downwards in free air; let it be amalgamated,
and have a drop of mercury suspended from it; and
then let it be powerfully electrized. The mercury
will present the phenomenon of glow; a current
of air will rush along the rod, and set off from the
mercury directly downwards; and the form of the metallic
drop will be slightly affected, the convexity at a
small part near the middle and lower part becoming
greater, whilst it diminishes all round at places
a little removed from this spot. The change is
from the form of a (fi.) to that of b,
and is due almost, if not entirely, to the mechanical
force of the current of air sweeping over its surface.
1582. As a comparative observation,
let it be noticed, that a ball gradually brought towards
it converts the glow into brushes, and ultimately
sparks pass from the most projecting part of the mercury.
A point does the same, but at much smaller distances.
1583. Take next a drop of strong
solution of muriate of lime; being electrified, a
part will probably be dissipated, but a considerable
portion, if the electricity be not too powerful, will
remain, forming a conical drop (fi.), accompanied
by a strong current. If glow be produced, the
drop will be smooth on the surface. If a short
low brush is formed, a minute tremulous motion of
the liquid will be visible; but both effects coincide
with the principal one to be observed, namely, the
regular and successive charge of air, the formation
of a wind or current, and the form given by that current
to the fluid drop, if a discharge ball be gradually
brought toward the cone, sparks will at last pass,
and these will be from the apex of the cone to the
approached ball, indicating a considerable degree
of conducting power in this fluid.
1584. With a drop of water, the
effects were of the same kind, and were best obtained
when a portion of gum water or of syrup hung from a
ball (fi.). When the machine was worked
slowly, a fine large quiet conical drop, with concave
lateral outline, and a small rounded end, was produced,
on which the glow appeared, whilst a steady wind issued,
in a direction from the point of the cone, of sufficient
force to depress the surface of uninsulated water
held opposite to the termination. When the machine
was worked more rapidly some of the water was driven
off; the smaller pointed portion left was roughish
on the surface, and the sound of successive brush
discharges was heard. With still more electricity,
more water was dispersed; that which remained was
elongated and contracted, with an alternating motion;
a stronger brush discharge was heard, and the vibrations
of the water and the successive discharges of the individual
brushes were simultaneous. When water from beneath
was brought towards the drop, it did not indicate
the same regular strong contracted current of air
as before; and when the distance was such that sparks
passed, the water beneath was attracted rather
than driven away, and the current of air ceased.
1585. When the discharging ball
was brought near the drop in its first quiet glowing
state (1582.), it converted that glow into brushes,
and caused the vibrating motion of the drop.
When still nearer, sparks passed, but they were always
from the metal of the rod, over the surface of the
water, to the point, and then across the air to the
ball. This is a natural consequence of the deficient
conducting power of the fluid (1584. 1585.).
1586. Why the drop vibrated,
changing its form between the periods of discharging
brushes, so as to be more or less acute at particular
instants, to be most acute when the brush issued forth,
and to be isochronous in its action, and how the quiet
glowing liquid drop, on assuming the conical form,
facilitated, as it were, the first action, are points,
as to theory, so evident, that I will not stop to
speak of them. The principal thing to observe
at present is, the formation of the carrying current
of air, and the manner in which it exhibits its existence
and influence by giving form to the drop.
1587. That the drop, when of
water, or a better conductor than water, is formed
into a cone principally by the current of air, is shown
amongst other ways (1594.) thus. A sharp point
being held opposite the conical drop, the latter soon
lost its pointed form; was retraced and became round;
the current of air from it ceased, and was replaced
by one from the point beneath, which, if the latter
were held near enough to the drop, actually blew it
aside, and rendered it concave in form.
1588. It is hardly necessary
to say what happened with still worse conductors than
water, as oil, or oil of turpentine; the fluid itself
was then spun out into threads and carried off, not
only because the air rushing over its surface helped
to sweep it away, but also because its insulating
particles assumed the same charged state as the particles
of air, and, not being able to discharge to them in
a much greater decree than the air particles themselves
could do, were carried off by the same causes which
urged those in their course. A similar effect
with melted sealing-wax on a metal point forms an
old and well-known experiment.
1589. A drop of gum water in
the exhausted receiver of the air-pump was not sensibly
affected in its form when electrified. When air
was let in, it begun to show change of shape when
the pressure was ten inches of mercury. At the
pressure of fourteen or fifteen inches the change was
more sensible, and as the air increased in density
the effects increased, until they were the same as
those in the open atmosphere. The diminished effect
in the rare air I refer to the relative diminished
energy of its current; that diminution depending,
in the first place, on the lower electric condition
of the electrified ball in the rarefied medium, and
in the next, on the attenuated condition of the dielectric,
the cohesive force of water in relation to rarefied
air being something like that of mercury to dense air
(1581.), whilst that of water in dense air may be compared
to that of mercury in oil of turpentine (1597.).
1590. When a ball is covered
with a thick conducting fluid, as treacle or syrup,
it is easy by inductive action to determine the wind
from almost any part of it (1577.); the experiment,
which before was of rather difficult performance,
being rendered facile in consequence of the fluid enabling
that part, which at first was feeble in its action,
to rise into an exalted condition by assuming a pointed
form.
1591. To produce the current,
the electric intensity must rise and continue at one
spot, namely, at the origin of the current, higher
than elsewhere, and then, air having a uniform and
ready access, the current is produced. If no
current be allowed (1574.), then discharge may take
place by brush or spark. But whether it be by
brush or spark, or wind, it seems very probable that
the initial intensity or tension at which a particle
of a given gaseous dielectric charges, or commences
discharge, is, under the conditions before expressed,
always the same (1410.).
1592. It is not supposed that
all the air which enters into motion is electrified;
on the contrary, much that is not charged is carried
on into the stream. The part which is really
charged may be but a small proportion of that which
is ultimately set in motion (1442.).
1593. When a drop of gum water
(1584.) is made negative, it presents a larger
cone than when made positive; less of the fluid is
thrown off, and yet, when a ball is approached, sparks
can hardly be obtained, so pointed is the cone, and
so free the discharge. A point held opposite to
it did not cause the retraction of the cone to such
an extent as when it was positive. All the effects
are so different from those presented by the positive
cone, that I have no doubt such drops would present
a very instructive method of investigating the difference
of positive and negative discharge in air and other
dielectrics (1480. 1501.).
1594. That I may not be misunderstood
(1587.), I must observe here that I do not consider
the cones produced as the result only of the
current of air or other insulating dielectric over
their surface. When the drop is of badly conducting
matter, a part of the effect is due to the electrified
state of the particles, and this part constitutes almost
the whole when the matter is melted sealing-wax, oil
of turpentine, and similar insulating bodies (1588.).
But even when the drop is of good conducting matter,
as water, solutions, or mercury, though the effect
above spoken of will then be insensible (1607.), still
it is not the mere current of air or other dielectric
which produces all the change of form; for a part is
due to those attractive forces by which the charged
drop, if free to move, would travel along the line
of strongest induction, and not being free to move,
has its form elongated until the sum of the
different forces tending to produce this form is balanced
by the cohesive attraction of the fluid. The
effect of the attractive forces are well shown when
treacle, gum water, or syrup is used; for the long
threads which spin out, at the same time that they
form the axes of the currents of air, which may still
be considered as determined at their points, are like
flexible conductors, and show by their directions
in what way the attractive forces draw them.
1595. When the phenomena of currents
are observed in dense insulating dielectrics, they
present us with extraordinary degrees of mechanical
force. Thus, if a pint of well-rectified and filtered
(1571.) oil of turpentine be put into a glass vessel,
and two wires be dipped into it in different places,
one leading to the electrical machine, and the other
to the discharging train, on working the machine the
fluid will be thrown into violent motion throughout
its whole mass, whilst at the same time it will rise
two, three or four inches up the machine wire, and
dart off jets from it into the air.
1596. If very clean uninsulated
mercury be at the bottom of the fluid, and the wire
from the machine be terminated either by a ball or
a point, and also pass through a glass tube extending
both above and below the surface of the oil of turpentine,
the currents can be better observed, and will be seen
to rush down the wire, proceeding directly from it
towards the mercury, and there, diverging in all directions,
will ripple its surface strongly, and mounting up
at the sides of the vessel, will return to re-enter
upon their course.
1597. A drop of mercury being
suspended from an amalgamated brass ball, preserved
its form almost unchanged in air (1581.); but when
immersed in the oil of turpentine it became very pointed,
and even particles of the metal could be spun out
and carried off by the currents of the dielectric.
The form of the liquid metal was just like that of
the syrup in air (1584.), the point of the cone being
quite as fine, though not so long. By bringing
a sharp uninsulated point towards it, it could also
be effected in the same manner as the syrup drop in
air (1587.), though not so readily, because of the
density and limited quantity of the dielectric.
1598. If the mercury at the bottom
of the fluid be connected with the electrical machine,
whilst a rod is held in the hand terminating in a ball
three quarters of an inch, less or more, in diameter,
and the ball be dipped into the electrified fluid,
very striking appearances ensue. When the ball
is raised again so as to be at a level nearly out of
the fluid, large portions of the latter will seem
to cling to it (fi.). If it be raised higher,
a column of the oil of turpentine will still connect
it with that in the basin below (fi.).
If the machine be excited into more powerful action,
this will become more bulky, and may then also be raised
higher, assuming the form (fi; and all the time
that these effects continue, currents and counter-currents,
sometimes running very close together, may be observed
in the raised column of fluid.
1599. It is very difficult to
decide by sight the direction of the currents in such
experiments as these. If particles of silk are
introduced they cling about the conductors; but using
drops of water and mercury the course of the fluid
dielectric seems well indicated. Thus, if a drop
of water be placed at the end of a rod (1571.) over
the uninsulated mercury, it is soon swept away in
particles streaming downwards towards the mercury.
If another drop be placed on the mercury beneath the
end of the rod, it is quickly dispersed in all directions
in the form of streaming particles, the attractive
forces drawing it into elongated portions, and the
currents carrying them away. If a drop of mercury
be hung from a ball used to raise a column of the
fluid (1598.), then the shape of the drop seems to
show currents travelling in the fluid in the direction
indicated by the arrows (fi.).
1600. A very remarkable effect
is produced on these phenomena, connected with positive
and negative charge and discharge, namely, that a ball
charged positively raises a much higher and larger
column of the oil of turpentine than when charged
negatively. There can be no doubt that this is
connected with the difference of positive and negative
action already spoken of (1480. 1525.), and tends
much to strengthen the idea that such difference is
referable to the particles of the dielectric rather
than to the charged conductors, and is dependent upon
the mode in which these particles polarize (1503.
1523.).
1601. Whenever currents travel
in insulating dielectrics they really effect discharge;
and it is important to observe, though a very natural
result, that it is indifferent which way the current
or particles travel, as with reversed direction their
state is reversed. The change is easily made,
either in air or oil of turpentine, between two opposed
rods, for an insulated ball being placed in connexion
with either rod and brought near its extremity, will
cause the current to set towards it from the opposite
end.
1602. The two currents often
occur at once, as when both terminations present brushes,
and frequently when they exhibit the glow (1531.).
In such cases, the charged particles, or many of them,
meet and mutually discharge each other (1518. 1612.).
If a smoking wax taper be held at the end of an insulating
rod towards a charged prime conductor, it will very
often happen that two currents will form, and be rendered
visible by its vapour, one passing as a fine filament
of smoky particles directly to the charged conductor,
and the other passing as directly from the same taper
wick outwards, and from the conductor: the principles
of inductric action and charge, which were referred
to in considering the relation of a carrier ball and
a conductor (1566.), being here also called into play.
1603. The general analogy and,
I think I may say, identity of action found to exist
as to insulation and conduction (1338. 1561.) when
bodies, the best and the worst in the classes of insulators
or conductors, were compared, led me to believe that
the phenomena of convection in badly conducting
media were not without their parallel amongst the best
conductors, such even as the metals. Upon consideration,
the cones produced by Davy in fluid metals, as
mercury and tin, seemed to be cases in point, and
probably also the elongation of the metallic medium
through which a current of electricity was passing,
described by Ampere (1113); for it is not difficult
to conceive, that the diminution of convective effect,
consequent upon the high conducting power of the metallic
media used in these experiments, might be fully compensated
for by the enormous quantity of electricity passing.
In fact, it is impossible not to expect some
effect, whether sensible or not, of the kind in question,
when such a current is passing through a fluid offering
a sensible resistance to the passage of the electricity,
and, thereby, giving proof of a certain degree of
insulating power (1328.).
1604. I endeavoured to connect
the convective currents in air, oil of turpentine,
&c. and those in metals, by intermediate cases, but
found this not easy to do. On taking bodies,
for instance, which, like water, adds, solutions,
fused salts or chlorides, &c., have intermediate conducting
powers, the minute quantity of electricity which the
common machine can supply (371. 861.) is exhausted
instantly, so that the cause of the phenomenon is
kept either very low in intensity, or the instant of
time during which the effect lasts is so small, that
one cannot hope to observe the result sought for.
If a voltaic battery be used, these bodies are all
electrolytes, and the evolution of gas, or the production
of other changes, interferes and prevents observation
of the effect required.
1605. There are, nevertheless,
some experiments which illustrate the connection.
Two platina wires, forming the electrodes of a powerful
voltaic battery, were placed side by side, near each
other, in distilled water, hermetically sealed up
in a strong glass tube, some minute vegetable fibres
being present in the water. When, from the evolution
of gas and the consequent increased pressure, the
bubbles formed on the electrodes were so small as
to produce but feebly ascending currents, then it could
be observed that the filaments present were attracted
and repelled between the two wires, as they would
have been between two oppositely charged surfaces
in air or oil of turpentine, moving so quickly as to
displace and disturb the bubbles and the currents
which these tended to form. Now I think it cannot
be doubted, that under similar circumstances, and with
an abundant supply of electricity, of sufficient tension
also, convective currents might have been formed;
the attractions and repulsions of the filaments were,
in fact, the elements of such currents (1572.), and
therefore water, though almost infinitely above air
or oil of turpentine as a conductor, is a medium in
which similar currents can take place.
1606. I had an apparatus made
(fi.) in which a is a plate of shell-lac,
b a fine platina wire passing through it, and
having only the section of the wire exposed above;
c a ring of bibulous paper resting on the shell-lac,
and d distilled water retained by the paper
in its place, and just sufficient in quantity to cover
the end of the wire b; another wire, e,
touched a piece of tinfoil lying in the water, and
was also connected with a discharging train; in this
way it was easy, by rendering b either positive
or negative, to send a current of electricity by its
extremity into the fluid, and so away by the wire e.
1607. On connecting b
with the conductor of a powerful electrical machine,
not the least disturbance of the level of the fluid
over the end of the wire during the working of the
machine could be observed; but at the same time there
was not the smallest indication of electrical charge
about the conductor of the machine, so complete was
the discharge. I conclude that the quantity of
electricity passed in a given time had been
too small, when compared with the conducting power
of the fluid to produce the desired effect.
1608. I then charged a large
Leyden battery (291.), and discharged it through the
wire b, interposing, however, a wet thread,
two feet long, to prevent a spark in the water, and
to reduce what would else have been a sudden violent
discharge into one of more moderate character, enduring
for a sensible length of time (334.). I now did
obtain a very brief elevation of the water over the
end of the wire; and though a few minute bubbles of
gas were at the same time formed there, so as to prevent
me from asserting that the effect was unequivocally
the same as that obtained by DAVY in the metals, yet,
according to my best judgement, it was partly, and
I believe principally, of that nature.
1609. I employed a voltaic battery
of 100 pair of four-inch plates for experiments of
a similar nature with electrolytes. In these cases
the shell-lac was cupped, and the wire b
0.2 of an inch in diameter. Sometimes I used
a positive amalgamated zinc wire in contact with dilute
sulphuric acid; at others, a negative copper wire in
a solution of sulphate of copper; but, because of
the evolution of gas, the precipitation of copper,
&c., I was not able to obtain decided results.
It is but right to mention, that when I made use of
mercury, endeavouring to repeat DAVY’s experiment,
the battery of 100 pair was not sufficient to produce
the elevations.
In the experiments at the Royal Institution,
Sir H. Davy used, I think, 500 or 600 pairs of plates.
Those at the London Institution were made with the
apparatus of Mr. Pepys (consisting of an enormous
single pair of plates), described in the Philosophical
Transactions for 1832, .
1610. The latter experiments
(1609.) may therefore be considered as failing to
give the hoped-for proof, but I have much confidence
in the former (1605. 1608.), and in the considerations
(1603.) connected with them. If I have rightly
viewed them, and we may be allowed to compare the currents
at points and surfaces in such extremely different
bodies as air and the metals, and admit that they
are effects of the same kind, differing only
in degree and in proportion to the insulating or conducting
power of the dielectric used, what great additional
argument we obtain in favour of that theory, which
in the phenomena of insulation and conduction also,
as in these, would link the same apparently
dissimilar substances together (1336. 1561.); and
how completely the general view, which refers all the
phenomena to the direct action of the molecules of
matter, seems to embrace the various isolated phenomena
as they successively come under consideration!
1611. The connection of this
convective or carrying effect, which depends upon
a certain degree of insulation, with conduction; i.e.
the occurrence of both in so many of the substances
referred to, as, for instance, the metals, water,
air, &c., would lead to many very curious theoretical
generalizations, which I must not indulge in here.
One point, however, I shall venture to refer to.
Conduction appears to be essentially an action of
contiguous particles, and the considerations just stated,
together with others formerly expressed (1326, 1336,
&c.), lead to the conclusion, that all bodies conduct,
and by the same process, air as well as metals; the
only difference being in the necessary degree of force
or tension between the particles which must exist
before the act of conduction or transfer from one
particle to another can take place.
1612. The question then arises,
what is this limiting condition which separates, as
it were, conduction and insulation from each other?
Does it consist in a difference between the two contiguous
particles, or the contiguous poles of these particles,
in the nature and amount of positive and negative
force, no communication or discharge occurring unless
that difference rises up to a certain degree, variable
for different bodies, but always the same for the
same body? Or is it true that, however small the
difference between two such particles, if time
be allowed, equalization of force will take place,
even with the particles of such bodies as air, sulphur
or lac? In the first case, insulating power
in any particular body would be proportionate to the
degree of the assumed necessary difference of force;
in the second, to the time required to equalize
equal degrees of difference in different bodies.
With regard to airs, one is almost led to expect a
permanent difference of force; but in all other bodies,
time seems to be quite sufficient to ensure, ultimately,
complete conduction. The difference in the modes
by which insulation may be sustained, or conduction
effected, is not a mere fanciful point, but one of
great importance, as being essentially connected with
the molecular theory of induction, and the manner
in which the particles of bodies assume and retain
their polarized state.
P xi. Relation of a vacuum to electrical phenomena.
1613. It would seem strange,
if a theory which refers all the phenomena of insulation
and conduction, i.e. all electrical phenomena,
to the action of contiguous particles, were to omit
to notice the assumed possible case of a vacuum.
Admitting that a vacuum can be produced, it would be
a very curious matter indeed to know what its relation
to electrical phenomena would be; and as shell-lac
and metal are directly opposed to each other, whether
a vacuum would be opposed to them both, and allow neither
of induction or conduction across it. Mr. Morgan
has said that a vacuum does not conduct. Sir
H. Davy concluded from his investigations, that as
perfect a vacuum as could be made did conduct, but
does not consider the prepared spaces which he used
as absolute vacua. In such experiments I think
I have observed the luminous discharge to be principally
on the inner surface of the glass; and it does not
appear at all unlikely, that, if the vacuum refused
to conduct, still the surface of glass next it might
carry on that action.
Philosophical Transactions, 1785,
Ibi, .
1614. At one time, when I thought
inductive force was exerted in right lines, I hoped
to illustrate this important question by making experiments
on induction with metallic mirrors (used only as conducting
vessels) exposed towards a very clear sky at night
time, and of such concavity that nothing but the firmament
could be visible from the lowest part of the concave
n, fi. Such mirrors, when electrified,
as by connexion with a Leyden jar, and examined by
a carrier ball, readily gave electricity at the lowest
part of their concavity if in a room; but I was in
hopes of finding that, circumstanced as before stated,
they would give little or none at the same spot, if
the atmosphere above really terminated in a vacuum.
I was disappointed in the conclusion, for I obtained
as much electricity there as before; but on discovering
the action of induction in curved lines (1231.), found
a full and satisfactory explanation of the result.
1615. My theory, as far as I
have ventured it, does not pretend to decide upon
the consequences of a vacuum. It is not at present
limited sufficiently, or rendered precise enough,
either by experiments relating to spaces void of matter,
or those of other kinds, to indicate what would happen
in the vacuum case. I have only as yet endeavoured
to establish, what all the facts seem to prove, that
when electrical phenomena, as those of induction,
conduction, insulation and discharge occur, they depend
on, and are produced by the action of contiguous
particles of matter, the next existing particle being
considered as the contiguous one; and I have further
assumed, that these particles are polarized; that each
exhibits the two forces, or the force in two directions
(1295. 1298.); and that they act at a distance, only
by acting on the contiguous and intermediate
particles.
1616. But assuming that a perfect
vacuum were to intervene in the course of the lines
of inductive action (1304.), it does not follow from
this theory, that the particles on opposite sides
of such a vacuum could not act on each other.
Suppose it possible for a positively electrified particle
to be in the centre of a vacuum an inch in diameter,
nothing in my present views forbids that the particle
should act at the distance of half an inch on all
the particles forming the inner superficies of the
bounding sphere, and with a force consistent with
the well-known law of the squares of the distance.
But suppose the sphere of an inch were full of insulating
matter, the electrified particle would not then, according
to my notion, act directly on the distant particles,
but on those in immediate association with it, employing
all its power in polarizing them; producing
in them negative force equal in amount to its own
positive force and directed towards the latter, and
positive force of equal amount directed outwards and
acting in the same manner upon the layer of particles
next in succession. So that ultimately, those
particles in the surface of a sphere of half an inch
radius, which were acted on directly when that
sphere was a vacuum, will now be acted on indirectly
as respects the central particle or source of action,
i.e. they will be polarized in the same way,
and with the same amount of force.
1617. The word current
is so expressive in common language, that when applied
in the consideration of electrical phenomena we can
hardly divest it sufficiently of its meaning, or prevent
our minds from being prejudiced by it (283. 511.).
I shall use it in its common electrical sense, namely,
to express generally a certain condition and relation
of electrical forces supposed to be in progression.
1618. A current is produced both
by excitement and discharge; and whatsoever the variation
of the two general causes may be, the effect remains
the same. Thus excitement may occur in many ways,
as by friction, chemical action, influence of heat,
change of condition, induction, &c.; and discharge
has the forms of conduction, electrolyzation, disruptive
discharge, and convection; yet the current connected
with these actions, when it occurs, appears in all
cases to be the same. This constancy in the character
of the current, notwithstanding the particular and
great variations which may be made in the mode of
its occurrence, is exceedingly striking and important;
and its investigation and development promise to supply
the most open and advantageous road to a true and intimate
understanding of the nature of electrical forces.
1619. As yet the phenomena of
the current have presented nothing in opposition to
the view I have taken of the nature of induction as
an action of contiguous particles. I have endeavoured
to divest myself of prejudices and to look for contradictions,
but I have not perceived any in conductive, electrolytic,
convective, or disruptive discharge.
1620. Looking at the current
as a cause, it exerts very extraordinary and
diverse powers, not only in its course and on the bodies
in which it exists, but collaterally, as in inductive
or magnetic phenomena.
1621. Electrolytic action.—One
of its direct actions is the exertion of pure chemical
force, this being a result which has now been examined
to a considerable extent. The effect is found
to be constant and definite for the
quantity of electric force discharged (783. &c.); and
beyond that, the intensity required is in relation
to the intensity of the affinity or forces to be overcome
(904. 906. 911.). The current and its consequences
are here proportionate; the one may be employed to
represent the other; no part of the effect of either
is lost or gained; so that the case is a strict one,
and yet it is the very case which most strikingly illustrates
the doctrine that induction is an action of contiguous
particles (1164. 1343.).
1622. The process of electrolytic
discharge appears to me to be in close analogy, and
perhaps in its nature identical with another process
of discharge, which at first seems very different
from it, I mean convection (1347. 1572.).
In the latter case the particles may travel for yards
across a chamber; they may produce strong winds in
the air, so as to move machinery; and in fluids, as
oil of turpentine, may even shake the hand, and carry
heavy metallic bodies about; and yet I do not see
that the force, either in kind or action, is at all
different to that by which a particle of hydrogen
leaves one particle of oxygen to go to another, or
by which a particle of oxygen travels in the contrary
direction.
If a metallic vessel three or four
inches deep, containing oil of turpentine, be insulated
and electrified, and a rod with a ball (an inch
or more in diameter) at the end have the ball immersed
in the fluid whilst the end is held in the hand,
the mechanical force generated when the ball is
moved to and from the sides of the vessel will soon
be evident to the experimenter.
1623. Travelling particles of
the air can effect chemical changes just as well as
the contact of a fixed platina electrode, or that of
a combining electrode, or the ions of a decomposing
electrolyte (453. 471.); and in the experiment formerly
described, where eight places of decomposition were
rendered active by one current (469.), and where charged
particles of air in motion were the only electrical
means of connecting these parts of the current, it
seems to me that the action of the particles of the
electrolyte and of the air were essentially the same.
A particle of air was rendered positive; it travelled
in a certain determinate direction, and coming to an
electrolyte, communicated its powers; an equal amount
of positive force was accordingly acquired by another
particle (the hydrogen), and the latter, so charged,
travelled as the former did, and in the same direction,
until it came to another particle, and transferred
its power and motion, making that other particle active.
Now, though the particle of air travelled over a visible
and occasionally a large space, whilst the particle
of the electrolyte moved over an exceedingly small
one; though the air particle might be oxygen, nitrogen,
or hydrogen, receiving its charge from force of high
intensity, whilst the electrolytic particle of hydrogen
had a natural aptness to receive the positive condition
with extreme facility; though the air particle might
be charged with very little electricity at a very high
intensity by one process, whilst the hydrogen particle
might be charged with much electricity at a very low
intensity by another process; these are not differences
of kind, as relates to the final discharging action
of these particles, but only of degree; not essential
differences which make things unlike, but such differences
as give to things, similar in their nature, that great
variety which fits them for their office in the system
of the universe.
1624. So when a particle of air,
or of dust in it, electrified at a negative point,
moves on through the influence of the inductive forces
(1572.) to the next positive surface, and after discharge
passes away, it seems to me to represent exactly that
particle of oxygen which, having been rendered negative
in the electrolyte, is urged by the same disposition
of inductive forces, and going to the positive platina
electrode, is there discharged, and then passes away,
as the air or dust did before it.
1625. Heat is another direct
effect of the current upon substances in which
it occurs, and it becomes a very important question,
as to the relation of the electric and heating forces,
whether the latter is always definite in amount.
There are many cases, even amongst bodies which conduct
without change, that at present are irreconcileable
with the assumption that it is; but there are also
many which indicate that, when proper limitations
are applied, the heat produced is definite. Harris
has shown this for a given length of current in a
metallic wire, using common electricity; and De
la Rive has proved the same point for voltaic electricity
by his beautiful application of Breguet’s thermometer.
1626. When the production of
heat is observed in electrolytes under decomposition,
the results are still more complicated. But important
steps have been taken in the investigation of this
branch of the subject by De la Rive and others;
and it is more than probable that, when the right
limitations are applied, constant and definite results
will here also be obtained.
1627. It is a most important
part of the character of the current, and essentially
connected with its very nature, that it is always the
same. The two forces are everywhere in it.
There is never one current of force or one fluid only.
Any one part of the current may, as respects the presence
of the two forces there, be considered as precisely
the same with any other part; and the numerous experiments
which imply their possible separation, as well as
the theoretical expressions which, being used daily,
assume it, are, I think, in contradiction with facts
(511, &c.). It appears to me to be as impossible
to assume a current of positive or a current of negative
force alone, or of the two at once with any predominance
of one over the other, as it is to give an absolute
charge to matter (516. 1169. 1177.).
1628. The establishment of this
truth, if, as I think, it be a truth, or on the other
hand the disproof of it, is of the greatest consequence.
If, as a first principle, we can establish, that the
centres of the two forces, or elements of force, never
can be separated to any sensible distance, or at all
events not further than the space between two contiguous
particles (1615.), or if we can establish the contrary
conclusion, how much more clear is our view of what
lies before us, and how much less embarrassed the
ground over which we have to pass in attaining to it,
than if we remain halting between two opinions!
And if, with that feeling, we rigidly test every experiment
which bears upon the point, as far as our prejudices
will let us (1161.), instead of permitting them with
a theoretical expression to pass too easily away,
are we not much more likely to attain the real truth,
and from that proceed with safety to what is at present
unknown?
1629. I say these things, not,
I hope, to advance a particular view, but to draw
the strict attention of those who are able to investigate
and judge of the matter, to what must be a turning
point in the theory of electricity; to a separation
of two roads, one only of which can be right:
and I hope I may be allowed to go a little further
into the facts which have driven me to the view I
have just given.
1630. When a wire in the voltaic
circuit is heated, the temperature frequently rises
first, or most at one end. If this effect were
due to any relation of positive or negative as respects
the current, it would be exceedingly important.
I therefore examined several such cases; but when,
keeping the contacts of the wire and its position to
neighbouring things unchanged, I altered the direction
of the current, I found that the effect remained unaltered,
showing that it depended, not upon the direction of
the current, but on other circumstances. So there
is here no evidence of a difference between one part
of the circuit and another.
1631. The same point, i.e.
uniformity in every part, may be illustrated by what
may be considered as the inexhaustible nature of the
current when producing particular effects; for these
effects depend upon transfer only, and do not consume
the power. Thus a current which will heat one
inch of platina wire will heat a hundred inches (853.
note). If a current be sustained in a constant
state, it will decompose the fluid in one voltameter
only, or in twenty others if they be placed in the
circuit, in each to an amount equal to that in the
single one.
1632. Again, in cases of disruptive
discharge, as in the spark, there is frequently a
dark part (1422.) which, by Professor Johnson, has
been called the neutral point; and this has given
rise to the use of expressions implying that there
are two electricities existing separately, which,
passing to that spot, there combine and neutralize
each other. But if such expressions are understood
as correctly indicating that positive electricity
alone is moving between the positive ball and that
spot, and negative electricity only between the negative
ball and that spot, then what strange conditions these
parts must be in; conditions, which to my mind are
every way unlike those which really occur! In
such a case, one part of a current would consist of
positive electricity only, and that moving in one
direction; another part would consist of negative electricity
only, and that moving in the other direction; and a
third part would consist of an accumulation of the
two electricities, not moving in either direction,
but mixing up together! and being in a relation to
each other utterly unlike any relation which could
be supposed to exist in the two former portions of
the discharge. This does not seem to me to be
natural. In a current, whatever form the discharge
may take, or whatever part of the circuit or current
is referred to, as much positive force as is there
exerted in one direction, so much negative force is
there exerted in the other. If it were not so
we should have bodies electrified not merely positive
and negative, but on occasions in a most extraordinary
manner, one being charged with five, ten, or twenty
times as much of both positive and negative electricity
in equal quantities as another. At present, however,
there is no known fact indicating such states.
Silliman’s Journal, 1834, xxv.
.
Thomson on Heat and Electricity, .
1633. Even in cases of convection,
or carrying discharge, the statement that the current
is everywhere the same must in effect be true (1627.);
for how, otherwise, could the results formerly described
occur? When currents of air constituted the mode
of discharge between the portions of paper moistened
with iodide of potassium or sulphate of soda (465.
469.), decomposition occurred; and I have since ascertained
that, whether a current of positive air issued from
a spot, or one of negative air passed towards it,
the effect of the evolution of iodine or of acid was
the same, whilst the reversed currents produced alkali.
So also in the magnetic experiments (307.) whether
the discharge was effected by the introduction of
a wire, or the occurrence of a spark, or the passage
of convective currents either one way or the other
(depending on the electrified state of the particles),
the result was the same, being in all cases dependent
upon the perfect current.
1634. Hence, the section of a
current compared with other sections of the same current
must be a constant quantity, if the actions exerted
be of the same kind; or if of different kinds, then
the forms under which the effects are produced are
equivalent to each other, and experimentally convertible
at pleasure. It is in sections, therefore, we
must look for identity of electrical force, even to
the sections of sparks and carrying actions, as well
as those of wires and electrolytes.
1635. In illustration of the
utility and importance of establishing that which
may be the true principle, I will refer to a few cases.
The doctrine of unipolarity, as formerly stated, and
I think generally understood, is evidently inconsistent
with my view of a current (1627.); and the later singular
phenomena of poles and flames described by Erman and
others partake of the same inconsistency of character.
If a unipolar body could exist, i.e. one that
could conduct the one electricity and not the other,
what very new characters we should have a right to
expect in the currents of single electricities passing
through them, and how greatly ought they to differ,
not only from the common current which is supposed
to have both electricities travelling in opposite
directions in equal amount at the same time, but also
from each other! The facts, which are excellent,
have, however, gradually been more correctly explained
by Becquerel, Andrews, and others; and I understand
that Professor Ohms has perfected the work, in
his close examination of all the phenomena; and after
showing that similar phenomena can take place with
good conductors, proves that with soap, &c. many of
the effects are the mere consequences of the bodies
evolved by electrolytic action.
Schweigger’s Jahrbuch de
Chimie, &. Heft 8. Not understanding
German, it is with extreme regret I confess I have
not access, and cannot do justice, to the many most
valuable papers in experimental electricity published
in that language. I take this opportunity also
of stating another circumstance which occasions me
great trouble, and, as I find by experience, may
make, me seemingly regardless of the labours of
others:—it is a gradual loss of memory
for some years past; and now, often when I read a
memoir, I remember that I have seen it before, and
would have rejoiced if at the right time I could
have recollected and referred to it in the progress
of my own papers.—M.F.
1636. I conclude, therefore,
that the facts upon which the doctrine of unipolarity
was founded are not adverse to that unity and indivisibility
of character which I have stated the current to possess,
any more than the phenomena of the pile itself (which
might well bear comparison with those of unipolar
bodies,) are opposed to it. Probably the effects
which have been called effects of unipolarity, and
the peculiar differences of the positive and negative
surface when discharging into air, gases, or other
dielectrics (1480. 1525.) which have been already referred
to, may have considerable relation to each other.
1637. M. de la Rive has recently
described a peculiar and remarkable effect of heat
on a current when passing between electrodes and a
fluid. It is, that if platina electrodes dip
into acidulated water, no change is produced in the
passing current by making the positive electrode hotter
or colder; whereas making the negative electrode hotter
increased the deflexion of a galvanometer affected
by the current, from 12 deg. to 30 deg. and
even 45 deg., whilst making it colder diminished
the current in the same high proportions.
1638. That one electrode should
have this striking relation to heat whilst the other
remained absolutely without, seem to me as incompatible
with what I conceived to be the character of a current
as unipolarity (1627. 1635.), and it was therefore
with some anxiety that I repeated the experiment.
The electrodes which I used were platina; the electrolyte,
water containing about one sixth of sulphuric acid
by weight: the voltaic battery consisted of two
pairs of amalgamated zinc and platina plates in dilute
sulphuric acid, and the galvanometer in the circuit
was one with two needles, and gave when the arrangement
was complete a deflexion of 10 deg. or 12 deg..
1639. Under these circumstances
heating either electrode increased the current; heating
both produced still more effect. When both were
heated, if either were cooled, the effect on the current
fell in proportion. The proportion of effect
due to heating this or that electrode varied, but on
the whole heating the negative seemed to favour the
passage of the current somewhat more than heating
the positive. Whether the application of heat
were by a flame applied underneath, or one directed
by a blowpipe from above, or by a hot iron or coal,
the effect was the same.
1640. Having thus removed the
difficulty out of the way of my views regarding a
current, I did not pursue this curious experiment further.
It is probable, that the difference between my results
and those of M. de la Rive may depend upon the relative
values of the currents used; for I employed only a
weak one resulting from two pairs of plates two inches
long and half an inch wide, whilst M. de la Rive used
four pairs of plates of sixteen square inches in surface.
1641. Electric discharges in
the atmosphere in the form of balls of fire have occasionally
been described. Such phenomena appear to me to
be incompatible with all that we know of electricity
and its modes of discharge. As time is
an element in the effect (1418. 1436.) it is possible
perhaps that an electric discharge might really pass
as a ball from place to place; but as every thing
shows that its velocity must be almost infinite, and
the time of its duration exceedingly small, it is
impossible that the eye should perceive it as anything
else than a line of light. That phenomena of
balls of fire may appear in the atmosphere, I do not
mean to deny; but that they have anything to do with
the discharge of ordinary electricity, or are at all
related to lightning or atmospheric electricity, is
much more than doubtful.
1642. All these considerations,
and many others, help to confirm the conclusion, drawn
over and over again, that the current is an indivisible
thing; an axis of power, in every part of which both
electric forces are present in equal amount (517.
1627.). With conduction and electrolyzation,
and even discharge by spark, such a view will harmonize
without hurting any of our preconceived notions; but
as relates to convection, a more startling result
appears, which must therefore be considered.
I am glad to refer here to the results
obtained by Mr. Christie with magneto-electricity,
Philosophical Transactions, 1833, note.
As regards the current in a wire, they confirm everything
that I am contending for.
1643. If two balls A and B be
electrified in opposite states and held within each
other’s influence, the moment they move towards
each other, a current, or those effects which are
understood by the word current, will be produced.
Whether A move towards B, or B move in the opposite
direction towards A, a current, and in both cases
having the same direction, will result.
If A and B move from each other, then a current
in the opposite direction, or equivalent effects,
will be produced.
1644. Or, as charge exists only
by induction (1178. 1299.), and a body when electrified
is necessarily in relation to other bodies in the opposite
state; so, if a ball be electrified positively in the
middle of a room and be then moved in any direction,
effects will be produced, as current in the
same direction (to use the conventional mode of expression)
had existed: or, if the ball be negatively electrified,
and then moved, effects as if a current in a direction
contrary to that of the motion had been formed, will
be produced.
1645. I am saying of a single
particle or of two what I have before said, in effect,
of many (1633.). If the former account of currents
be true, then that just stated must be a necessary
result. And, though the statement may seem startling
at first, it is to be considered that, according to
my theory of induction, the charged conductor or particle
is related to the distant conductor in the opposite
state, or that which terminates the extent of the
induction, by all the intermediate particles (1165,
1295.), these becoming polarized exactly as the particles
of a solid electrolyte do when interposed between
the two electrodes. Hence the conclusion regarding
the unity and identity of the current in the case of
convection, jointly with the former cases, is not
so strange as it might at first appear.
1646. There is a very remarkable
phenomenon or effect of the electrolytic discharge,
first pointed out, I believe, by Mr. Porrett, of the
accumulation of fluid under decomposing action in the
current on one side of an interposed diaphragm.
It is a mechanical result; and as the liquid passes
from the positive towards the negative electrode in
all the known cases, it seems to establish a relation
to the polar condition of the dielectric in which
the current exists (1164. 1525.). It has not as
yet been sufficiently investigated by experiment;
for De la Rive says, it requires that the water
should be a bad conductor, as, for instance, distilled
water, the effect not happening with strong solutions;
whereas, Dutrochet says the contrary is the case,
and that, the effect is not directly due to the electric
current.
1647. Becquerel, in his Traite
de l’Electricite, has brought together the
considerations which arise for and against the opinion,
that the effect generally is an electric effect.
Though I have no decisive fact to quote at present,
I cannot refrain from venturing an opinion, that the
effect is analogous both to combination and convection
(1623.), being a case of carrying due to the relation
of the diaphragm and the fluid in contact with it,
through which the electric discharge is jointly effected;
and further, that the peculiar relation of positive
and negative small and large surfaces already referred
to (1482. 1503. 1525.), may be the direct cause of
the fluid and the diaphragm travelling in contrary
but determinate directions. A very valuable experiment
has been made by M. Becquerel with particles of clay,
which will probably bear importantly on this point.
1648. As long as the terms
current and electro-dynamic are used
to express those relations of the electric forces
in which progression of either fluids or effects are
supposed to occur (283.), so long will the
idea of velocity be associated with them; and this
will, perhaps, be more especially the case if the
hypothesis of a fluid or fluids be adopted.
1649. Hence has arisen the desire
of estimating this velocity either directly or by
some effect dependent on it; and amongst the endeavours
to do this correctly, may be mentioned especially
those of Dr. Watson in 1748, and of Professor Wheatstone
in 1834; the electricity in the early trials being
supposed to travel from end to end of the arrangement,
but in the later investigations a distinction occasionally
appearing to be made between the transmission of the
effect and of the supposed fluid by the motion of
whose particles that effect is produced.
1650. Electrolytic action has
a remarkable bearing upon this question of the velocity
of the current, especially as connected with the theory
of an electric fluid or fluids. In it there is
an evident transfer of power with the transfer of
each particle of the anion or cathion present, to the
next particles of the cathion or anion; and as the
amount of power is definite, we have in this way a
means of localizing as it were the force, identifying
it by the particle and dealing it out in successive
portions, which leads, I think, to very striking results.
1651. Suppose, for instance,
that water is undergoing decomposition by the powers
of a voltaic battery. Each particle of hydrogen
as it moves one way, or of oxygen as it moves in the
other direction, will transfer a certain amount of
electrical force associated with it in the form of
chemical affinity (822. 852. 918.) onwards through
a distance, which is equal to that through which the
particle itself has moved. This transfer will
be accompanied by a corresponding movement in the
electrical forces throughout every part of the circuit
formed (1627. 1634.), and its effects may be estimated,
as, for instance, by the heating of a wire (853.) at
any particular section of the current however distant.
If the water be a cube of an inch in the side, the
electrodes touching, each by a surface of one square
inch, and being an inch apart, then, by the time that
a tenth of it, or 25.25 grs., is decomposed, the particles
of oxygen and hydrogen throughout the mass may be
considered as having moved relatively to each other
in opposite directions, to the amount of the tenth
of an inch; i.e. that two particles at first
in combination will after the motion be the tenth
of an inch apart. Other motions which occur in
the fluid will not at all interfere with this result;
for they have no power of accelerating or retarding
the electric discharge, and possess in fact no relation
to it.
1652. The quantity of electricity
in 25.25 grains of water is, according to an estimate
of the force which I formerly made (861.), equal to
above 24 millions of charges of a large Leyden battery;
or it would have kept any length of a platina wire
1/104 of an inch in diameter red-hot for an hour and
a half (853.). This result, though given only
as an approximation, I have seen no reason as yet
to alter, and it is confirmed generally by the experiments
and results of M. Pouillet. According to Mr.
Wheatstone’s experiments, the influence or effects
of the current would appear at a distance of 576,000
miles in a second. We have, therefore, in this
view of the matter, on the one hand, an enormous quantity
of power equal to a most destructive thunder-storm
appearing instantly at the distance of 576,000 miles
from its source, and on the other, a quiet effect,
in producing which the power had taken an hour and
a half to travel through the tenth of an inch:
yet these are the equivalents to each other, being
effects observed at the sections of one and the same
current (1634.).
1653. It is time that I should
call attention to the lateral or transverse forces
of the current. The great things which
have been achieved by Oersted, Arago, Ampere, Davy,
De la Rive, and others, and the high degree of simplification
which has been introduced into their arrangement by
the theory of Ampere, have not only done their full
service in advancing most rapidly this branch of knowledge,
but have secured to it such attention that there is
no necessity for urging on its pursuit. I refer
of course to magnetic action and its relations; but
though this is the only recognised lateral action
of the current, there is great reason for believing
that others exist and would by their discovery reward
a close search for them (951.).
1654. The magnetic or transverse
action of the current seems to be in a most extraordinary
degree independent of those variations or modes of
action which it presents directly in its course; it
consequently is of the more value to us, as it gives
us a higher relation of the power than any that might
have varied with each mode of discharge. This
discharge, whether it be by conduction through a wire
with infinite velocity (1652.), or by electrolyzation
with its corresponding and exceeding slow motion (1651.),
or by spark, and probably even by convection, produces
a transverse magnetic action always the same in kind
and direction.
1655. It has been shown by several
experimenters, that whilst the discharge is of the
same kind the amount of lateral or magnetic
force is very constant (216. 366. 367. 368. 376.).
But when we wish to compare discharge of different
kinds, for the important purpose of ascertaining whether
the same amount of current will in its different
forms produce the same amount of transverse action,
we find the data very imperfect. Davy noticed,
that when the electric current was passing through
an aqueous solution it affected a magnetic needle,
and Dr. Ritchie says, that the current in the electrolyte
is as magnetic as that in a metallic wire, and has
caused water to revolve round a magnet as a wire carrying
the current would revolve.
1656. Disruptive discharge produces
its magnetic effects: a strong spark, passed
transversely to a steel needle, will magnetise it as
well as if the electricity of the spark were conducted
by a metallic wire occupying the line of discharge;
and Sir H. Davy has shown that the discharge of a
voltaic battery in vacuo is affected and has motion
given to it by approximated magnets.
1657. Thus the three very different
modes of discharge, namely, conduction, electrolyzation,
and disruptive discharge, agree in producing the important
transverse phenomenon of magnetism. Whether convection
or carrying discharge will produce the same phenomenon
has not been determined, and the few experiments I
have as yet had time to make do not enable me to answer
in the affirmative.
1658. Having arrived at this
point in the consideration of the current and in the
endeavour to apply its phenomena as tests of the truth
or fallacy of the theory of induction which I have
ventured to set forth, I am now very much tempted
to indulge in a few speculations respecting its lateral
action and its possible connexion with the transverse
condition of the lines of ordinary induction (1165,
1304.). I have long sought and still seek for
an effect or condition which shall be to statical electricity
what magnetic force is to current electricity (1411.);
for as the lines of discharge are associated with
a certain transverse effect, so it appeared to me
impossible but that the lines of tension or of inductive
action, which of necessity precede that discharge,
should also have their correspondent transverse condition
or effect (951.).
1659. According to the beautiful
theory of Ampere, the transverse force of a current
may be represented by its attraction for a similar
current and its repulsion of a contrary current.
May not then the equivalent transverse force of static
electricity be represented by that lateral tension
or repulsion which the lines of inductive action appear
to possess (1304.)? Then again, when current
or discharge occurs between two bodies, previously
under inductrical relations to each other, the lines
of inductive force will weaken and fade away, and,
as their lateral repulsive tension diminishes, will
contract and ultimately disappear in the line of discharge.
May not this be an effect identical with the attractions
of similar currents? i.e. may not the passage
of static electricity into current electricity, and
that of the lateral tension of the lines of inductive
force into the lateral attraction of lines of similar
discharge, have the same relation and dependences,
and run parallel to each other?
1660. The phenomena of induction
amongst currents which I had the good fortune to discover
some years ago (6. &.) may perchance here form
a connecting link in the series of effects. When
a current is first formed, it tends to produce a current
in the contrary direction in all the matter around
it; and if that matter have conducting properties and
be fitly circumstanced, such a current is produced.
On the contrary, when the original current is stopped,
one in the same direction tends to form all around
it, and, in conducting matter properly arranged, will
be excited.
1661. Now though we perceive
the effects only in that portion of matter which,
being in the neighbourhood, has conducting properties,
yet hypothetically it is probable, that the nonconducting
matter has also its relations to, and is affected
by, the disturbing cause, though we have not yet discovered
them. Again and again the relation of conductors
and non-conductors has been shown to be one not of
opposition in kind, but only of degree (1334, 1603.);
and, therefore, for this, as well as for other reasons,
it is probable, that what will affect a conductor will
affect an insulator also; producing perhaps what may
deserve the term of the electrotonic state (60. 242.
1114.).
1662. It is the feeling of the
necessity of some lateral connexion between the lines
of electric force (1114.); of some link in the chain
of effects as yet unrecognised, that urges me to the
expression of these speculations. The same feeling
has led me to make many experiments on the introduction
of insulating dielectrics having different inductive
capacities (1270. 1277.) between magnetic poles and
wires carrying currents, so as to pass across the
lines of magnetic force. I have employed such
bodies both at rest and in motion, without, as yet,
being able to detect any influence produced by them;
but I do by no means consider the experiments as sufficiently
delicate, and intend, very shortly, to render them
more decisive.
1663. I think the hypothetical
question may at present be put thus: can such
considerations as those already generally expressed
(1658.) account for the transverse effects of electrical
currents? are two such currents in relation to each
other merely by the inductive condition of the particles
of matter between them, or are they in relation by
some higher quality and condition (1654.), which,
acting at a distance and not by the intermediate particles,
has, like the force of gravity, no relation to them?
1664. If the latter be the case,
then, when electricity is acting upon and in matter,
its direct and its transverse action are essentially
different in their nature; for the former, if I am
correct, will depend upon the contiguous particles,
and the latter will not. As I have said before,
this may be so, and I incline to that view at present;
but I am desirous of suggesting considerations why
it may not, that the question may be thoroughly sifted.
1665. The transverse power has
a character of polarity impressed upon it. In
the simplest forms it appears as attraction or repulsion,
according as the currents are in the same or different
directions: in the current and the magnet it
takes up the condition of tangential forces; and in
magnets and their particles produces poles. Since
the experiments have been made which have persuaded
me that the polar forces of electricity, as in induction
and electrolytic action (1298. 1343.), show effects
at a distance only by means of the polarized contiguous
and intervening particles, I have been led to expect
that all polar forces act in the same general
manner; and the other kinds of phenomena which one
can bring to bear upon the subject seem fitted to
strengthen that expectation. Thus in crystallizations
the effect is transmitted from particle to particle;
and in this manner, in acetic acid or freezing water
a crystal a few inches or even a couple of feet in
length will form in less than a second, but progressively
and by a transmission of power from particle to particle.
And, as far as I remember, no case of polar action,
or partaking of polar action, except the one under
discussion, can be found which does not act by contiguous
particles. It is apparently of the nature of
polar forces that such should be the case, for the
one force either finds or developed the contrary force
near to it, and has, therefore, no occasion to seek
for it at a distance.
I mean by contiguous particles those
which are next to each other,
not that there is no space between
them. See (1616.).
1666. But leaving these hypothetical
notions respecting the nature of the lateral action
out of sight, and returning to the direct effects,
I think that the phenomena examined and reasoning
employed in this and the two preceding papers tend
to confirm the view first taken (1464.), namely, that
ordinary inductive action and the effects dependent
upon it are due to an action of the contiguous particles
of the dielectric interposed between the charged surfaces
or parts which constitute, as it were, the terminations
of the effect. The great point of distinction
and power (if it have any) in the theory is, the making
the dielectric of essential and specific importance,
instead of leaving it as it were a mere accidental
circumstance or the simple representative of space,
having no more influence over the phenomena than the
space occupied by it. I have still certain other
results and views respecting the nature of the electrical
forces and excitation, which are connected with the
present theory; and, unless upon further consideration
they sink in my estimation, I shall very shortly put
them into form as another series of these electrical
researches.
Royal Institution. February
14th, 1838.